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PU matte white finish stable in gloss and permanently smooth and preparation method thereof

A white topcoat, permanent technology, applied in coatings, polyester coatings, etc., can solve the problems of uneven gloss of the paint film, blooming, ordinary PU matte clear can not meet the needs of high-end coating, etc., to achieve stable gloss, Good instant leveling effect

Inactive Publication Date: 2016-12-14
GUANGDONG BADESE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] When spraying ordinary PU matt white topcoat, all paint technology practitioners know that fumed silica is mainly used for matting gloss paint film, but due to the characteristics of fumed silica, it is affected by construction technology, drying time, Environmental temperature and humidity, anti-settling effect and other factors are greatly affected, especially in the production of low-gloss white finish paint, if the amount of fumed silica is large, the paint film is prone to problems such as uneven gloss and blooming; organic Silicone and wax powder are suspended on the surface of the paint film to provide a touch. The paint film is rubbed on the furniture over time and during use. After the paint film is worn out, the silicone and wax powder give the film a silky touch. will disappear
As high-end furniture is more and more popular among consumers, the coating requirements are also increasing, and ordinary PU matte clear is far from meeting the high-end coating requirements.

Method used

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  • PU matte white finish stable in gloss and permanently smooth and preparation method thereof
  • PU matte white finish stable in gloss and permanently smooth and preparation method thereof
  • PU matte white finish stable in gloss and permanently smooth and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Prepare 60% solid content white paste: first take 34.6% of short oil alkyd resin, 0.2% of fumed silica, 4% of xylene and 1.2% of dispersant (copolymer solution containing acidic groups) and mix by weight percentage. Disperse at 800 rpm for 7 minutes, then add 60% rutile titanium dioxide at 600 rpm, stir and disperse at 1200 rpm for 18 minutes, and finally grind to fineness ≤ 20um.

[0037] Preparation of component A: add 60% solid content white pulp 45%, short oil alkyd resin 13%, 6900-20X anti-settling wax 5%, anti-settling mud 2%, and modified polyurethane in the dispersion tank according to the weight percentage. Polymer dispersant 1.7%, silicone leveling agent 0.2%, defoamer (a solution of foam-breaking polymer and polysiloxane) 0.3% and MIBK 1.5%, stir at 600r / min until uniform, then add poly Tetrafluoroethylene wax powder 0.3% and ED-30 matte powder 1%, stir and disperse at 1200r / min for 15min until the fineness is ≤25um, and then add 20% solid content chlorinated vi...

Embodiment 2

[0042] Prepare 60% solid content white paste: first take 34.6% of short oil alkyd resin, 0.2% of fumed silica, 4% of xylene and 1.2% of dispersant (copolymer solution containing acidic groups) and mix by weight percentage. Disperse for 3 minutes at 1000 rpm, then add 60% rutile titanium dioxide at 800 rpm, stir and disperse at 1500 rpm for 12 minutes, and finally grind to fineness ≤ 20um.

[0043] Preparation of component A: Add 60% solid content of white pulp 52.6%, short oil alkyd resin 12%, 6900-20X anti-wax 4%, anti-settling 1.8%, and modified polyurethane in the dispersion tank according to weight percentage. Polymer dispersant 1.5%, silicone leveling agent 0.3%, defoamer (a solution of foam-breaking polymer and polysiloxane) 0.4% and MIBK 1.2%, stir at 700r / min until uniform, then add polytetrafluoroethylene Vinyl fluoride wax powder 0.4% and ED-30 matte powder 0.8%, stir and disperse at 1300r / min for 13 minutes to a fineness of ≤25um, and then add 20% solid content 12% vin...

Embodiment 3

[0048] Prepare 60% solid content white paste: first take 34.6% of short oil alkyd resin, 0.2% of fumed silica, 4% of xylene and 1.2% of dispersant (copolymer solution containing acidic groups) and mix by weight percentage. Disperse for 5 minutes at 900 rpm, then add 60% rutile titanium dioxide at 700 rpm, stir and disperse at 1300 rpm for 15 minutes, and finally grind to fineness ≤ 20um.

[0049] Preparation of component A: add 60% solid content white pulp 60%, short oil alkyd resin 10%, 6900-20X anti-wax 3.5%, anti-settling 1.5%, and modified polyurethane in the dispersion tank according to weight percentage. Polymer dispersant 1%, silicone leveling agent 0.5%, defoamer (a solution of foam-breaking polymer and polysiloxane) 0.5% and MIBK 1.0%, stir at 800r / min until uniform, then add polytetrafluoroethylene Vinyl fluoride wax powder 0.5% and ED-30 matte powder 0.5%, stir and disperse at 1500r / min for 10min until the fineness is ≤25um, and then add 20% solid content chlorovinegar...

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Abstract

The invention provides PU matte white finish stable in gloss and permanently smooth and a preparation method thereof. The PU matte white finish is prepared in the steps that white paste with the solid content being 60%, short oil alkyd resin, PE matting wax slurry, 6900-20X anti-sediment wax, anti-sediment slurry, wetting dispersant, a flatting agent, a defoaming agent, MIBK, vinyl chloride-vinyl acetate resin solution with the solid content being 20%, ED-30 matt powder, polytetrafluoroethylene wax powder and the like are prepared from a first component; a 1451 light trimer curing agent, a TDI additive product curing agent, an HDI trimer curing agent, MIBK, MEK and n-butyl acetate are prepared into a second component; methylbenzene, n-butyl acetate, acetic ether, MEK and propylene glycol methyl ether acetate are prepared into a third component; the first component, the second component and the third component are evenly mixed according to the proportion. Detection and trial prove that a paint film obtained after the PU matte white finish is sprayed is good in leveling property and high in sagging resistance, dazzled does not happen if the white finish is coated thin, the white finish can be kept permanently smooth, gloss is stable, and the PU matte white finish is suitable for coating of high-furniture and other wood products.

Description

Technical field [0001] The invention belongs to the wood coating manufacturing industry, and specifically relates to the research and development of a PU matte white topcoat with stable gloss and permanent smoothness. Background technique [0002] When ordinary PU matte white finish paint is sprayed, all paint technical practitioners know that the gloss paint film matting is mainly made of fumed silica, but due to the characteristics of fumed silica, it is affected by the construction process, drying time, Environmental temperature and humidity, anti-settling effect and other factors have great influence, especially in the production of low-gloss white topcoats, if the amount of fumed silica is large, the paint film is prone to uneven gloss, blooming and other paint film defects; use organic Silicon and wax powder are suspended on the surface of the paint film to provide a feel. The paint film is constantly rubbed on the furniture over time and in use. After the paint film is wor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D167/08C09D127/06C09D7/12C09D7/02C09D7/00C09D7/45
CPCC08L2205/02C08L2205/025C08L2205/035C09D167/08C08L67/08C08L27/06C08L27/18C08K13/02C08K3/36C08K2003/2241
Inventor 方学平严修才杨长春
Owner GUANGDONG BADESE CHEM
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