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A kind of highly transparent and antifouling coating solution and preparation method thereof

A coating solution and high-transparency technology, applied in antifouling/underwater coatings, biocide-containing paints, coatings, etc., can solve the problems of poor dirt resistance, high surface activity, and easy entry of films, and achieve improved Anti-fouling ability, reduced surface activity, good anti-fouling effect

Active Publication Date: 2018-08-31
WUJIANG CSG GLASS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the anti-reflection film obtained by the sol-gel process is mainly composed of silica, and the refractive index of its dense structure is about 1.45. Now the anti-reflection coating solution on the market adopts a loose and porous structure to improve the transmittance. That is, the structure of openings or through holes, but this structural feature will make it easy for pollutants or water vapor in the environment to enter the interior of the film or adhere to the surface of the film, thereby affecting the transmittance of the film and making the film show poor performance. At the same time, in the prior art, due to the presence of a large number of hydroxyl groups on the surface of the inorganic silica anti-reflection film, the surface activity is very high, and it is easy to adhere to pollutants, which reduces the transmittance of the film

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A high-transparency anti-fouling coating solution and a preparation method thereof, comprising the following steps:

[0028] A. Film-forming substance solution: in parts by weight, mix 4 parts of ethyl orthosilicate, 12 parts of isopropanol, 2.3 parts of KH560, and 1.5 parts of phenyltrimethoxysilane in order, stir for 60 minutes, add the mixed Acid solution (pure water and 37% concentrated hydrochloric acid are 1 part and 0.03 part respectively), stirred and heated to 60 ° C, the reaction time is 8 hours, cooled to room temperature and aged for 24 hours;

[0029] B. Sealing substance solution: mix 8 parts of propylene glycol methyl ether, 1 part of polyether-modified polysiloxane, and 2 parts of polyethylene glycol in parts by weight at room temperature, stir for 30 minutes, and then let stand 1h;

[0030] C. Pore-forming substance solution: in parts by weight, 1 part of methacrylic resin stock solution is evenly dispersed in 5 parts of isopropanol, stirred for 30 min...

Embodiment 2

[0033] A high-transparency anti-fouling coating solution and a preparation method thereof, comprising the following steps:

[0034] A. Film-forming substance solution: in parts by weight, mix 5 parts of ethyl orthosilicate, 15 parts of isopropanol, 2.4 parts of KH560, and 2.2 parts of phenyltrimethoxysilane in order, stir for 60 minutes, and add the mixed Acid solution (pure water and 37% concentrated hydrochloric acid are 1.4 parts and 0.04 parts respectively), stirred and heated to 80 ° C, the reaction time is 4 hours, cooled to room temperature and aged for 36 hours;

[0035] B. Sealing substance solution: mix 10 parts of propylene glycol methyl ether, 1.5 parts of polyether-modified polysiloxane, and 3 parts of polyethylene glycol in parts by weight at room temperature, stir for 30 minutes, and then let stand 1h;

[0036] C. Pore-forming substance solution: in parts by weight, 1.5 parts of methacrylic resin stock solution was uniformly dispersed in 6 parts of isopropanol,...

Embodiment 3

[0039] A high-transparency anti-fouling coating solution and a preparation method thereof, comprising the following steps:

[0040] A. Film-forming substance solution: in parts by weight, mix 4 parts of ethyl orthosilicate, 12 parts of isopropanol, 2.5 parts of KH570, and 2.1 parts of diphenyldimethoxysilane in order, stir for 60 minutes, add and mix The acid solution (pure water and 37% concentrated hydrochloric acid are 1 part and 0.03 parts respectively), stirred and heated to 80 ° C, the reaction time is 4 hours, cooled to room temperature and aged for 24 hours;

[0041] B. Sealing substance solution: mix 10 parts of propylene glycol methyl ether, 1 part of polyether-modified polysiloxane, and 2 parts of polyethylene glycol in parts by weight at room temperature, stir for 30 minutes, and then let stand 1h;

[0042] C. Pore-forming substance solution: in parts by weight, 1 part of methacrylic resin stock solution is evenly dispersed in 5 parts of isopropanol, stirred for 3...

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Abstract

The invention discloses a high-transmittance and anti-fouling coating solution and a preparation method thereof. The preparation method comprises the following steps that 1, a film forming matter solution is uniformly dispersed into a solvent by taking isopropanol as a main solvent under the room temperature condition; 2, a hole sealing structure matter solution and a hole forming matter solution are added into a dispersion solution prepared in the step 1 separately under the high-speed stirring condition; 3, the solution prepared in the step 2 is uniformly stirred and subjected to standing for 1 hour, and then the coating solution can be prepared. According to the coating solution, hole sealing structure matter and a functional auxiliary are used, the good anti-fouling property is provided while the high transmittance is guaranteed, and the condition of widely applying the coating solution to the field of optical devices such as solar cells, photovoltaic glass and flat-panel displayers is met.

Description

technical field [0001] The invention relates to the field of anti-reflection films, in particular to a high-transparency and anti-pollution coating solution and a preparation method thereof. Background technique [0002] Anti-reflection coatings are widely used in solar cells, photovoltaic glass, flat panel displays and other optical devices to reduce the reflection of light from interfaces. At present, the anti-reflection film obtained by the sol-gel process is mainly composed of silica, and the refractive index of its dense structure is about 1.45. Now the anti-reflection coating solution on the market adopts a loose and porous structure to improve the transmittance. That is, the structure of openings or through holes, but this structural feature will make it easy for pollutants or water vapor in the environment to enter the interior of the film or adhere to the surface of the film, thereby affecting the transmittance of the film and making the film show poor performance. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D1/00C09D5/16C09D7/65C09D7/20
CPCC09D1/00C09D5/1656C09D5/1687
Inventor 毛强强康正辉
Owner WUJIANG CSG GLASS CO LTD
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