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Residue oil hydrotreating catalyst grading method and residue oil hydrotreating method

A technology for residual oil hydrogenation and catalyst, which is applied in the fields of hydrogenation treatment process, hydrocarbon oil treatment, petroleum industry, etc. It can solve the problem of low denitrification ability in removing impurities, reduce the amount of carbon deposition in the catalyst, and prolong the operation cycle , evenly distributed effect

Active Publication Date: 2018-11-30
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The purpose of the present invention is to provide a new residual oil hydrogenation method to overcome the defect that the catalytic system obtained by the existing residual oil hydrotreating catalyst grading method has low impurity removal ability (especially denitrification ability) Catalyst grading method and residual oil hydrotreating method

Method used

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  • Residue oil hydrotreating catalyst grading method and residue oil hydrotreating method

Examples

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Effect test

Embodiment 1

[0050] This example is used to illustrate the catalyst grading method for residual oil hydrotreating and the method for residual oil hydrotreating provided by the present invention.

[0051] The reactor is filled with G1, M1, S1 and N1 sequentially from front to back, and the filling volume ratio is 5:35:30:30. The residual oil and hydrogen were mixed and then injected into the reactor for hydrotreating. The conditions of hydrotreating are shown in Table 3, and the removal rate of impurities is shown in Table 4.

Embodiment 2

[0055] This example is used to illustrate the catalyst grading method for residual oil hydrotreating and the method for residual oil hydrotreating provided by the present invention.

[0056] According to the method of Example 1, the residual oil hydrotreating is carried out, the difference is that the reactor is filled with G1, M1, S2, N2 and N1 sequentially from front to back, and the filling volume ratio is 5:35:30:15:15, Its impurity removal rate is shown in Table 4.

Embodiment 3

[0060] This example is used to illustrate the catalyst grading method for residual oil hydrotreating and the method for residual oil hydrotreating provided by the present invention.

[0061] The raw material oil and test conditions in this example are the same as in Example 1. The reactor is filled with G1, M1, S2 and N1 in sequence from front to back, and the filling volume ratio is 5:35:30:30. The removal rate of impurities is shown in the table 4.

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Abstract

The invention relates to a residual oil hydrotreatment catalyst grading method and a residual oil hydrotreatment method. The residual oil hydrotreatment catalyst grading method comprises that a residual oil hydrotreatment device is orderly filled with a hydrogenation protection catalyst, a hydrogenation metal-removal catalyst, a hydrodesulfurization catalyst and a hydrodenitrogenation catalyst along a material flowing direction and is characterized in that along a material flowing direction, the total acid amount of the catalysts is gradually increased, a ratio of Lewis acid to the total acids is gradually decreased and a ratio of Bronsted acid to the total acids is gradually increased. The residual oil hydrotreatment method comprises pouring residual oil into the residual oil hydrotreatment device. The residual oil hydrotreatment device is filled with the catalysts according to the above grading method. In residual oil hydrotreatment, the residual oil hydrotreatment catalyst grading method substantially improves a denitrification rate.

Description

technical field [0001] The invention relates to a catalyst gradation method for residual oil hydrogenation treatment and a residual oil hydrogenation treatment method. Background technique [0002] The main purpose of the fixed-bed residual oil hydrotreating process is to remove a large number of impurities contained in the residual oil raw material, such as sulfur, nitrogen, metals and asphaltenes, and to provide raw materials for the catalytic cracking unit. The main reactions in this process include hydrodemetallization, hydrodesulfurization, hydrodenitrogenation, saturation of aromatics, and hydrocracking of hydrocarbons. The early fixed-bed residual oil hydroprocessing technology was mainly desulfurization, but in recent years, with the progress of fixed-bed residual oil hydroprocessing technology and catalytic cracking technology, the focus of fixed-bed residual oil hydroprocessing technology has changed from desulfurization It is used for carbon removal, nitrogen rem...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G65/02
Inventor 邓中活戴立顺牛传峰刘涛邵志才董凯施瑢杨清河
Owner CHINA PETROLEUM & CHEM CORP
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