Low-temperature type lithium ion battery with high voltage and high volume energy density
A lithium-ion battery and energy density technology, applied in the field of lithium-ion batteries, can solve the problems of increased lithium-ion diffusion resistance, poor low-temperature performance of lithium-ion batteries, and reduced safety performance and cycle performance.
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Embodiment 1
[0039]a. Preparation of positive electrode sheet: 4.35V modified lithium cobaltate, conductive carbon black and polyvinylidene fluoride (PVDF) are mixed with solvent nitrogen methyl pyrrolidone (NMP) according to the mass percentage of 96.5::1.5:2. Positive electrode slurry, coated on a double-sided glossy aluminum foil with a thickness of 12 μm and a material of 1060, with a coating surface density of 40.2 mg / cm 2 , after coating, carry out roll pressing to make a positive electrode sheet for later use, and the compacted density is 4.2g / cm 3 ;
[0040] b. Preparation of negative electrode sheet: natural graphite and artificial graphite are mixed into a negative electrode active material according to a mass ratio of 1:1, and then the negative electrode active material, conductive carbon black and polyvinylidene fluoride (PVDF) are 96% by mass : The ratio of 1:3 is mixed with the solvent nitrogen methyl pyrrolidone (NMP) to make negative electrode slurry, which is coated on a ...
Embodiment 2
[0045] a. Preparation of positive electrode sheet: 4.40V lithium cobaltate, conductive carbon nanotubes (CNTS) and polyvinylidene fluoride (PVDF) are mixed with solvent nitrogen methyl pyrrolidone (NMP) according to the ratio of mass percentage of 97.5:1:1.5 Make a positive electrode slurry, and coat it on a double-sided aluminum foil with a thickness of 12 μm and a material of 1060, and the coating surface density is 42.4 mg / cm 2 , after coating, carry out roll pressing to make a positive electrode sheet for later use, and the compacted density is 4.2g / cm 3 ;
[0046] b. Preparation of negative electrode sheet: natural graphite and artificial graphite are mixed into a negative electrode active material according to a mass ratio of 1:1, and then the negative electrode active material, conductive carbon black and polyvinylidene fluoride (PVDF) are 96.5% by mass : The ratio of 0.5:3 is mixed with the solvent nitrogen methyl pyrrolidone (NMP) to make negative electrode slurry, w...
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