Chromium-free composite resin gel-type profile control agent for oil exploitation and preparation method and application thereof
A technology of composite resin and profile control agent, applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of continuous improvement of profile control effect, increased post-processing burden, environmental pollution, etc., and achieve excellent oil recovery effect , good application prospects and the effect of industrialized production potential
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preparation example 1
[0096] Preparation Example 1: Preparation of Nano-Silica Modified Crosslinked Polymer
[0097] A1: the preparation of pre-polymerized cross-linking agent solution, which comprises the following steps:
[0098] A1-1: Add phenol and formaldehyde solution with a concentration of 37% by mass into the reactor (the molar ratio of phenol to formaldehyde in the formaldehyde solution is 0.75:1), stir and mix thoroughly, and then heat up to 70°C to obtain the reaction solution;
[0099] A1-2: Add kaolin-supported basic catalyst CAT to the reaction solution (the mass volume ratio of the kaolin-supported basic catalyst CAT to the reaction solution is 1:60g / ml), and continue to stir and react at 70°C for 35 minutes, Then naturally cool to room temperature and filter to separate the catalyst, and the filtrate is the prepolymerized crosslinking agent solution;
[0100] A2: Add anionic polyacrylamide with a degree of hydrolysis of 15-17% and a molecular weight of 15 million into deionized w...
preparation example 1-1—1-4
[0103] Preparation example 1-1—1-4: Preparation of nano-silica modified cross-linked polymer
preparation example 1-1
[0104] Preparation Example 1-1: Except that the catalyst in step A1-2 is replaced by DCAT by CAT, other operations are all the same, thus Repeat Preparation Example 1 to obtain Preparation Example 1-1, the obtained nano-silica The modified cross-linked polymer was named DJHW1.
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