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Halogen-free flame-retardant polypropylene material and preparation method thereof

A flame retardant polypropylene and polypropylene resin technology, applied in the field of polymer materials and their preparation, can solve problems such as affecting production efficiency, increasing production processes, increasing production costs, etc. Affect and ensure the effect of stability

Active Publication Date: 2015-11-18
JIANGYIN SULI CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This document uses a hyperdispersant with a special structure in combination with stearic acid and oxidized polyethylene wax to effectively treat the surface with piperazine pyrophosphate, so as to achieve the effect of resistance to hydrolysis and non-migration, which not only greatly increases the production cost, but also increases the production cost. The production process is affected, which affects the production efficiency

Method used

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  • Halogen-free flame-retardant polypropylene material and preparation method thereof
  • Halogen-free flame-retardant polypropylene material and preparation method thereof
  • Halogen-free flame-retardant polypropylene material and preparation method thereof

Examples

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Embodiment 1)

[0025] The halogen-free flame-retardant polypropylene material of this embodiment is made of the following components by weight:

[0026] 100kg of polypropylene resin, 14kg of piperazine diphosphate, 8kg of pentaerythritol diphosphate melamine salt, 2.5kg of melamine cyanurate, 2.5kg of organic montmorillonite, 10kg of EPDM rubber, 0.03kg The antioxidant 1010 and the antioxidant 168 of 0.07kg.

[0027] The preparation method of the above-mentioned halogen-free flame-retardant polypropylene material has the following steps:

[0028] ① Pour the above-mentioned components into the high-speed mixer according to the formula, start the motor, and control the agitator to rotate at 900 rpm for mixing until the friction heat generated by the mixing makes the temperature of the material rise to 90°C-100°C. Material cooling.

[0029] ② Feed the cooled mixture into a twin-screw extruder for melting and extrusion, and the extruded strips are cooled in a water tank, drawn into a pelletize...

Embodiment 2~ Embodiment 6)

[0032] The preparation method of the halogen-free flame-retardant polypropylene material of each example is the same as that of Example 1, the difference lies in the weight ratio of each component, see Table 1 for details.

[0033] Table 1

[0034]

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Abstract

The invention discloses a halogen-free flame-retardant polypropylene material and a preparation method thereof. The halogen-free flame-retardant polypropylene material comprises components in parts by weight as follows: 100 parts of polypropylene resin, 20-35 parts of a halogen-free composite flame retardant, 5-20 parts of a toughening agent and 0.05-0.12 parts of a complex antioxidant, wherein the halogen-free composite flame retardant comprises diphosphonate piperazine, pentaerythritol diphosphate melamine salt, melamine urate and organic montmorillonite in the weight ratio being (5-20) : (5-20) : (1-5) : (1:5). According to the halogen-free flame-retardant polypropylene material, a halogen-free composite flame retardant system comprises diphosphonate piperazine, pentaerythritol diphosphate melamine salt, melamine urate and organic montmorillonite and has an excellent flame-retardant synergistic effect and excellent high-temperature resistance, particularly, hydrolysis-resistant performance can be acquired without any treatment, and the flame retardant system is not easily hydrolyzed in the forming process.

Description

technical field [0001] The invention relates to a polymer material and a preparation method thereof, in particular to a halogen-free flame-retardant polypropylene material and a preparation method thereof. Background technique [0002] Polypropylene is widely used in the manufacture of components such as electronic appliances, auto parts, and modern office supplies due to its good heat resistance, low water absorption, and high comprehensive mechanical properties. However, due to the disadvantage of flammability of polypropylene, its application in some fields is limited. [0003] Currently used flame retardant polypropylene materials include halogen / antimony flame retardant polypropylene and halogen-free flame retardant polypropylene materials. The former type of flame-retardant polypropylene is prone to secondary disasters due to thermal cracking and a large amount of corrosive toxic gases and smoke generated during combustion. Therefore, according to the application and...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/16C08L23/08C08K13/02C08K3/34C08K5/521C08K5/3492B29C47/92B29C48/92
CPCB29C48/92B29C2948/92209B29C2948/92704C08L23/12C08L2201/02C08L2201/08C08L2201/22C08L2205/02C08L23/16C08K13/02C08K3/346C08K5/521C08K5/34924C08K5/51C08L23/0815C08K5/1345C08K5/526C08K5/34928C08K5/5205
Inventor 周健周仕龙汪焕平姜冉
Owner JIANGYIN SULI CHEM
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