Polyurethane material and preparation method thereof
A polyurethane material and polyurethane prepolymer technology, which is applied in the field of polyurethane materials and their preparation, can solve the problems of air pollution, high toxicity, and the release time of nutrients cannot be matched with the time of fertilizer, and achieves the effects of avoiding pollution, good strength and toughness.
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[0037] The invention provides a kind of preparation method of polyurethane material, comprising:
[0038] A) one or more of toluene diisocyanate and p-phenylene diisocyanate react with polyols to obtain the first polyurethane prepolymer;
[0039] One or more of 4,4'-diphenylmethane diisocyanate and naphthalene diisocyanate reacts with a polyhydroxy compound to obtain a second polyurethane prepolymer;
[0040] B) reacting the first polyurethane prepolymer, the second polyurethane prepolymer and the chain extender to obtain a polyurethane material.
[0041] In the present invention, firstly, one or more of phenylene diisocyanate and p-phenylene diisocyanate are reacted with polyhydroxyl compounds to obtain the first polyurethane prepolymer.
[0042]In the present invention, the polyhydroxy compound is preferably selected from polyhydroxy vegetable oils, including but not limited to castor oil, hydroxylated soybean oil, hydroxylated tung oil and hydroxylated sunflower oil one o...
Embodiment 1
[0081] First, the natural soybean oil is modified and processed into soybean oil polyols: add 218g soybean oil (SO) and 73.5g maleic anhydride (MA), place the four-necked bottle in a heating mantle, install stirring, condensing water, Thermometer and nitrogen protection. React at 210°C for 3 hours to obtain the intermediate maleic anhydride-modified soybean oil (SOMA). Then, 238.5 g of diethylene glycol and 0.12 g of KOH were added into the four-neck flask, and the temperature of the heating mantle was raised to 220° C. for 6 h to obtain crude soybean oil polyol. Remove unreacted diethylene glycol by washing with water several times and separating liquids; add 3% water, remove the water by distillation under reduced pressure, remove the adsorbent and potassium salt by suction filtration, and obtain the soybean oil polyol (SOP) required for the reaction , 1mol SOP contains 3mol of hydroxyl groups.
[0082] Mix the obtained SOP and toluene diisocyanate at a molar ratio of 1:2,...
Embodiment 2
[0088] Firstly, the natural tung oil is modified and processed into dihydroxy lycine ester: tung oil, glycerol are mixed with a molar ratio of 1:2, and the mass fraction is 0.5% sodium methoxide as a catalyst and added to a mixer, a condenser, A four-neck flask with a thermometer and a nitrogen conduit. Under the condition of 200°C, react for 4h. During the reaction, with N 2 Protect. Add 40ml of saturated sodium chloride aqueous solution to the prepared mixture, and use the properties that tung oil and dihydroxy lycate are insoluble in water, but glycerol and sodium methylate are soluble in water, so that tung oil and dihydroxy lycate can be suspended on water , separated by a separatory funnel to obtain a mixture of tung oil and dihydroxy lycate. The mixture was heated in a vacuum oven for 8 hours to obtain a stratified product with the upper layer being tung oil and the lower layer being dihydroxylung oleic acid ester, which was separated by a separatory funnel. Repeat ...
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