Preparation method of polypropylene foamed beads

A foaming bead and polypropylene technology, applied in the field of polymers, can solve the problems of high melting point, high molding temperature, increased energy consumption and manufacturing cost, etc.

Active Publication Date: 2015-10-14
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing high-rigidity polypropylene resin has a relatively high melting point, so a high molding temperature is required in the molding process, and high-pressure steam needs to be used, so special high-pressure-resistant molding equipment is required to achieve the foamed PP beads. Sufficient melt adhesion between them, thus increasing energy consumption and manufacturing cost

Method used

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  • Preparation method of polypropylene foamed beads
  • Preparation method of polypropylene foamed beads
  • Preparation method of polypropylene foamed beads

Examples

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preparation example Construction

[0045] Preparation of matrix resin HMSPP501

[0046] The polymerization reaction was carried out on a polypropylene pilot plant. Its main equipment includes prepolymerization reactor, first loop reactor and second loop reactor.

[0047] Pre-polymerization reaction: the main catalyst (DQ-III catalyst, provided by Beijing Aoda Branch of Sinopec Catalyst Company) with a flow rate of about 0.5g / hr, the co-catalyst (triethylaluminum) with a flow rate of 6.33g / hr, and a flow rate of 0.63 g / hr of the first external electron donor (dicyclopentyldimethoxysilane, DCPMS) was pre-contacted at 6°C for 20 minutes, and then continuously added to the continuous stirred tank prepolymerization reactor for prepolymerization reaction. Prepolymerization It is carried out under the environment of the propylene liquid phase body, the temperature is 15°C, and the residence time is about 4 minutes. Under these conditions, the prepolymerization ratio of the catalyst is about 120 to 150 times. The mol...

Embodiment 1~10

[0058] 1) Preparation of polypropylene resin particles: put 100 parts by weight of matrix resin, 0.05 parts by weight of cell nucleating agent (silicon dioxide) and additives into a high-speed mixer and mix at high speed for 30 seconds, then add LabLine100 microparticle preparation system , the torque is controlled at about 65%, the speed is 300rpm, and the polypropylene resin particles are obtained by underwater pelletizing. Wherein, the matrix resin used in Examples 1-5 is HMSPP501, and the matrix resin used in Examples 6-10 is HMSPP502. The additives used in Examples 1-10 all include 0.2 parts by weight of antioxidant 1010 (BASF company), 0.1 part by weight of antioxidant 168 (by BASF company) and 0.05 parts by weight of calcium stearate. Specifically, after blending the matrix resin, cell nucleating agent and additives with a high-speed mixer, extruding through a twin-screw extruder, introducing a temperature of 75°C or below, preferably 70°C or below, more preferably 55-6...

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Abstract

The invention provides a preparation method of polypropylene foamed beads. The preparation method comprises the steps of preparing polypropylene according to a following method, adding organic peroxides into obtained polypropylene serving as matrix resin, and foaming by virtue of a physical foaming agent, so as to obtain the polypropylene foamed beads, wherein the method of polypropylene comprises the step of carrying out propylene polymerization reaction including two or more stages in two or more reactors which are connected in series for operation, wherein external electron donors used in the two stages are respectively alkane compounds and diether compounds. According to the preparation method, high-melt-strength polypropylene with wide molecular weight distribution is taken as a raw material, the organic peroxides are taken as a surface modifier of EPP beads, and the closed-hole-structured polypropylene foamed beads having the advantages that the diameters of foamed holes are uniform, the foamed holes are compact and the hole distribution is uniform can be prepared; the polypropylene foamed beads can be applied to the fields such as automobile manufacturing, packaging, building insulation, sport equipment, living goods, aerospace and the like.

Description

technical field [0001] The invention relates to the field of macromolecules, in particular to a method for preparing polypropylene foam beads. Background technique [0002] Polypropylene resin is used in many fields because of its excellent mechanical properties, machinability, high heat resistance, high cost performance and recyclability. Due to the consideration of light weight and rigidity, the use of polypropylene to prepare non-crosslinked foam materials has become the focus of attention in the fields of packaging materials, building materials, and heat insulation materials. In order to obtain products with different shapes and special uses, expanded polypropylene beads (EPP) have become the focus of development. Products of various shapes can be prepared by high-temperature steam molding using EPP. [0003] In the field of automobile manufacturing, PP moldings have been used in various parts, such as sun visors, car interiors, bumper cores, trunk lids, car roofs and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/12C08L23/12C08L23/14C08K13/02C08K5/14C08F10/06C08F4/649C08F4/646
Inventor 郭鹏吕明福张师军徐耀辉毕福勇尹华杨庆泉
Owner CHINA PETROLEUM & CHEM CORP
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