Gas separation membrane
A gas separation membrane, general-form technology, applied in separation methods, semi-permeable membrane separation, dispersed particle separation, etc., can solve problems such as chemical structure limitation, difficulty in designing chemical structure considering processability, strength and separation performance, etc. Excellent film properties
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[0154] Hereafter, although an Example demonstrates this invention concretely, this invention is not limited to these Examples.
[0155] [Preparation of polyimide film]
[0156] The preparation of the HFIP group-containing asymmetric polyimide membrane for the gas separation membrane will be described.
[0157] Add 2.01g (3.78mmol) of the following HFA-3,4'-ODA, 1.68g (3.78mmol) of 6FDA, and 14g of N,N-dimethylacetamide to a 200mL three-necked flask equipped with a nitrogen gas introduction tube and a reflux cooler, After stirring at room temperature under a nitrogen atmosphere for 18 hours, 0.66 g (8.32 mmol) of pyridine and 0.77 g (7.56 mmol) of acetic anhydride were added, and the mixture was further stirred at room temperature for 3 hours. The resulting reaction liquid was heated up to 200° C., stirred for further 6 hours, and then cooled to room temperature. A homogeneous N,N-dimethylacetamide solution in which polyimide 1 was dissolved was obtained. The Mw of the polyi...
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