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Method for preparing conductive macromolecular composite material with isolation structure

A technology of polymer materials and conductive polymers, which is applied in the field of preparing conductive polymer composite materials with an isolation structure, can solve the problems of high conductive polymer composite material production efficiency and low percolation value, and achieve easy popularization and application, over The effect of low permeation value and simple process

Active Publication Date: 2015-04-22
ZHENGZHOU UNIV
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Problems solved by technology

[0004] The purpose of the present invention is mainly aimed at the problem that the conductive polymer composite material prepared by the traditional injection molding technology has a relatively high percolation value and the production efficiency of the conductive polymer composite material prepared by the traditional hot pressing molding technology is extremely low, and proposes a method for preparing A new method with low permeation value, high molding efficiency, good processability and based on general polymer materials

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  • Method for preparing conductive macromolecular composite material with isolation structure
  • Method for preparing conductive macromolecular composite material with isolation structure
  • Method for preparing conductive macromolecular composite material with isolation structure

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Embodiment 1-6

[0039] Embodiment 1-6 Preparation of Conductive Polymer Composite Material with Isolation Structure

[0040] Concrete preparation steps are:

[0041] (1) Pretreatment of multi-walled carbon nanotubes (CNTs): 20g of CNTs will be weighed on an analytical balance, then put into an open petri dish, put the petri dish into an oven, and set the oven temperature to 50 °C for 2 hours; then put the dried CNTs into ziplock bags and seal them for the next step.

[0042] (2) Preparation of CNTs / iPP / UHMWPE mixture: In order to make the mixture grind as fully as possible and maintain the consistency of the experimental conditions, the total mass of the mixture for each grinding is stipulated as 8g, and the mass ratio of iPP to UHMWPE is kept as 60 / 40, the content of the configured CNTs is respectively 1.34% (volume ratio, the same below, Example 1), 2.26% (Example 2), 2.73% (Example 3), 3.20% (Example 4), 3.68% % (Example 5), 4.65% (Example 6). First, weigh the mass of CNTs, iPP and UHMW...

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Abstract

The invention belongs to the technical field of conductive macromolecular materials and particularly relates to a method for preparing a conductive macromolecular composite material with an isolation structure. The invention provides the method for preparing the conductive macromolecular composite material with the isolation structure. The preparation method comprises the following steps: uniformly mixing two macromolecular materials and conductive particles by adopting a mechanical blending method to obtain a macromolecular material / conductive particle blending material, wherein the conductive particles are selectively distributed between interfaces of the two macromolecular materials to form a conductive network; and then, injection moulding the macromolecular material / conductive particle blending material by adopting a plunger injection moulding device to prepare the conductive macromolecular composite material with the isolation structure. According to the method provided by the invention, the conductive particles are selectively distributed between the two macromolecules to form the conductive network so as to form the so-called isolation structure, thus the percolation threshold of the material is reduced to a great extent. The invention provides a new concept for preparing the conductive macromolecular composite material which is low in percolation threshold, good in processing performance and extremely high in moulding efficiency.

Description

technical field [0001] The invention belongs to the technical field of conductive polymer materials, and in particular relates to a method for preparing a conductive polymer composite material with an isolation structure. Background technique [0002] As a functional polymer composite material, conductive polymer material expands the application range of polymer materials. Conductive polymer materials have become one of the research hotspots in the field of materials because they are widely used in antistatic materials, electrostatic shielding materials, self-temperature control materials and aerospace and other fields. Conductive polymer materials are divided into composite conductive polymer materials and structural conductive polymer composite materials according to different preparation methods. Conductive polymer composites (CPCs) are based on high molecular polymers, adding various conductive fillers such as carbon black (CB), carbon nanotubes (CNTs), graphene, metal ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/12C08K9/04C08K9/00C08K7/24B29C45/76
CPCB02C19/08B29C45/53B29C45/54B29C45/77B29C45/78B29C2945/76658B29C2945/76732B29K2995/0005C08K2201/001C08K2201/011C08L23/06C08L2207/068C08L23/12C08K9/00C08K7/24
Inventor 代坤翟威李卓李勇郑国强刘春太申长雨
Owner ZHENGZHOU UNIV
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