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Mono-ammonium phosphate produced by using wet process phosphoric acid and production method of mono-ammonium phosphate

A technology of monoammonium phosphate and wet-process phosphoric acid, which is applied in the direction of phosphate, phosphorus oxyacid, etc., can solve the problems of reducing the production cost of monoammonium phosphate products, polluting the crop growth environment, and difficult to control impurity content, and achieves the improvement of fluorine content , Improve the effect of purity and quality

Inactive Publication Date: 2015-03-25
GUIZHOU KAILIN GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the traditional process of producing monoammonium phosphate using wet-process phosphoric acid, wet-process phosphoric acid is used to directly react with ammonia, and the total nutrient is adjusted by controlling the molar ratio of ammonia to phosphoric acid, so that all impurities in wet-process phosphoric acid enter the product, resulting in The content of impurities such as total nutrients, water-soluble phosphorus and fluorine in the product is difficult to control and cannot meet market demand
[0003] Moreover, the fluorine content in monoammonium phosphate is high, which limits the scope of use of fertilizers. At the same time, due to the existence of various impurity elements, the effect of fertilization and the short-board theory of wooden barrels have an impact on crops. Obviously, the crop growth environment has been seriously polluted. For this reason, through long-term exploration and research, this researcher has provided a new option for the production of monoammonium phosphate products using wet-process phosphoric acid, reducing the production of monoammonium phosphate. Product production cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A kind of monoammonium phosphate produced by wet process phosphoric acid, the fluorine content of the monoammonium phosphate is 0.53%.

[0026] The production method of the monoammonium phosphate that this utilizes wet-process phosphoric acid to produce may further comprise the steps:

[0027] (1) Pre-neutralization: place phosphoric acid in the pre-neutralization tank, pass ammonia gas into it, and adopt the method of stirring while passing in, the stirring speed during stirring is 30r / min, and the When the molar ratio of ammonia gas to phosphoric acid is 0.5, continue to maintain the stirring speed for 20 minutes, and carry out heating treatment on the pre-neutralization tank, the heating rate is 0.3 ℃ / min heating treatment, and detect the mixed liquid in the pre-neutralization tank PH value, when the PH value reaches 0.5, stop the heating treatment, and obtain a solid-liquid mixture for use;

[0028] (2) Separation: the solid-liquid mixture obtained in step 1) is pl...

Embodiment 2

[0035] A kind of monoammonium phosphate produced by wet process phosphoric acid, the fluorine content of the monoammonium phosphate is 0.48%.

[0036] The production method of the monoammonium phosphate that this utilizes wet-process phosphoric acid to produce may further comprise the steps:

[0037] (1) Pre-neutralization: Place phosphoric acid in the pre-neutralization tank, pass ammonia gas into it, and adopt the method of stirring while passing in, and the stirring speed during stirring is 50r / min. When the molar ratio of ammonia gas to phosphoric acid is 0.7, continue to maintain the stirring speed for 30 minutes, and carry out the temperature rise treatment on the pre-neutralization tank, and the heating rate is 0.6 °C / min. PH value, when the PH value reaches 0.8, stop the heating treatment, and obtain a solid-liquid mixture for use;

[0038] (2) Separation: the solid-liquid mixture obtained in step 1) is placed in a centrifuge for centrifugation. The rotating speed of ...

Embodiment 3

[0045] A monoammonium phosphate produced by wet process phosphoric acid, the fluorine content of the monoammonium phosphate is 0.68%.

[0046] The production method of the monoammonium phosphate that this utilizes wet-process phosphoric acid to produce may further comprise the steps:

[0047] (1) Pre-neutralization: place phosphoric acid in the pre-neutralization tank, pass ammonia gas into it, and adopt the method of stirring while passing in, and the stirring speed during stirring is 40r / min, and when it is passed into When the molar ratio of ammonia gas to phosphoric acid is 0.6, continue to maintain the stirring speed for 25 minutes, and carry out heating treatment on the pre-neutralization tank, the heating rate is 0.5 ℃ / min heating treatment, and detect the mixed liquid in the pre-neutralization tank PH value, when the PH value reaches 0.7, stop the heating treatment, and obtain a solid-liquid mixture for use;

[0048] (2) Separation: Place the solid-liquid mixture obta...

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Abstract

The invention relates to the technical field of mono-ammonium phosphate prepared by using wet process phosphoric acid, and in particular to mono-ammonium phosphate produced by using wet process phosphoric acid and a production method of the mono-ammonium phosphate. When an ammonia gas is introduced or liquid ammonia is added into impurities in phosphoric acid prepared by using the wet process phosphoric acid, the neutralization in mixed liquor is adjusted to 0.5-0.8 to generate a large amount of precipitates from the impurities in the phosphoric acid, separation treatment is carried out by using a separator, after phosphoric acid with higher purity is obtained, the ammonia gas or the liquid ammonia is introduced in the phosphoric acid, and the pH value of the phosphoric acid is controlled to obtain mono-ammonium phosphate slurry with higher purity, so that the purity of a mono-ammonium phosphate product is improved and the total nutrient in the mono-ammonium phosphate is 60.15-60.36%, wherein counted by phosphorus pentoxide, the phosphorus content is 49.0-51.0%, the content of water soluble phosphorus is 47.62-48.15%, the nitrogen content is 9.0-11.0%, the fluorine content is 0.48-0.68%, the quality of the ammonium phosphate is improved, and the environmental pollution of the ammonium phosphate resulting from a fertilization effect is avoided.

Description

technical field [0001] The invention relates to the technical field of preparing monoammonium phosphate by wet-process phosphoric acid, in particular to monoammonium phosphate produced by wet-process phosphoric acid and a production method thereof. Background technique [0002] Monoammonium phosphate is a high-efficiency compound fertilizer except diammonium phosphate. Because of its high nutrient content, it is also widely used in various plant fertilization. With the continuous development of agricultural technology, people have a deeper understanding of the growth mechanism of plants, and the requirements for fertilizer efficiency and impurity content are getting higher and higher. At present, the requirement for water-soluble phosphorus in monoammonium phosphate is more than 90% of the total phosphorus, and the requirement for fluorine content is not higher than 1%. In the traditional process of producing monoammonium phosphate using wet-process phosphoric acid, wet-pro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B25/28
Inventor 魏发展廖吉星朱飞武石秀明
Owner GUIZHOU KAILIN GRP CO LTD
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