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Tempered boroaluminosilicate glass free of color change

A technology of boroaluminosilicate and glass, which is applied in glass tempering, glass manufacturing equipment, glass/slag layered products, etc., and can solve problems such as difficult concentration, consumption, and easy discoloration

Inactive Publication Date: 2014-12-24
SCHOTT GLASS TECH (SUZHOU) CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, with such low AgNO 3 The concentration may cause two problems as follows: one problem is that, as worried in US2012 / 0034435A1, it is difficult to form a high enough silver ion concentration on the glass surface to achieve excellent antimicrobial properties; another problem is that, according to our Calculate and repeat test results, for AgNO 3 and KNO 3 Such a small amount of AgNO in the mixed salt bath 3 , is easily consumed in the large-scale practical production of antimicrobial touch screen protective glass, which means that the AgNO must be accurately controlled in this salt bath 3 Concentration is very difficult
Silver-containing ion exchange is considered to be one of the most cost-effective methods of producing this glass. However, ordinary glass is prone to discoloration in silver-containing ion exchange, which has become a major difficulty in the popularization and application of this technology.

Method used

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  • Tempered boroaluminosilicate glass free of color change
  • Tempered boroaluminosilicate glass free of color change
  • Tempered boroaluminosilicate glass free of color change

Examples

Experimental program
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Effect test

Embodiment 1

[0165] The CS and DoL values ​​of Example 1 and Example 4 were measured by the FSM-6000 surface stress meter developed and produced by Japan Orihara Research Institute. These two values ​​are usually used to characterize the strength of glass after thermal tempering or chemical tempering. Tempered glass has a higher CS value, which generally means it is less prone to breakage at the same thickness. A large DoL value means that even if some deep scratches appear on the glass surface, the tempered glass can still maintain its strength unaffected. However, in the case of thin glass itself, too high CS plus too deep DoL will increase the risk of self-burst of the glass, because in this case, the tensile stress at the center of the glass will become very high. powerful.

[0166] The 4-point bend (4PB) method is another commonly used technique for measuring the strength of flat glass. This method measures the maximum load force (F) of the glass substrate and calculates the streng...

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Abstract

The invention relates to chemically tempered antimicrobial boroaluminosilicate glass free of color change. The boroaluminosilicate glass is characterized in that the content of B2O3 can meet the following relational expression as shown in the specification, wherein M2O is the sum of content of all monovalent metal oxides in the glass; MO is the sum of content of all divalent metal oxides in the glass; RO is the sum of all multivalent element oxides with potential reducing capacity in the glass; all content in the formula is based on mole percents of oxides; and the content of RO is based on the mole percents of the oxide with the highest cation valence. The glass can be tempered in a salt bath containing 0-5wt% of silver nitrate, so that high strength and excellent antibacterial property are obtained in one step; and high transmittance and colorless features are kept. The glass can be used as protecting glass of touch screens of mobile phones or other electronic equipment, can also be used as surfaces of any high-strength, scratch-resistant, transparent and antimicrobial equipment and apparatuses, which are frequently touched by people in hospitals and communal facilities, or even the surfaces of buildings.

Description

technical field [0001] The present invention relates generally to boroaluminosilicate glass which can be chemically toughened, and further relates to boroaluminosilicate glass which has no discoloration after being chemically toughened in a silver-containing salt bath. Antimicrobial boroaluminosilicate glass, and more particularly, the present invention relates to antimicrobial boroaluminosilicate glass chemically toughened by exchanging silver ions with alkali metal ions in the glass to achieve antimicrobial and no discoloration, and its Manufacturing method. In particular, the present invention relates to cover glass, back glass for devices with touch screens, such as mobile electronic devices. Background technique [0002] Electronic devices with touch screens, such as tablet computers and mobile phones, have become more and more popular in people's daily life. Glass is widely used on these devices to protect their touch screens and improve the user experience at the sa...

Claims

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Application Information

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IPC IPC(8): C03C3/091C03C3/097C03C3/095C03C3/093C03C3/118C03B27/03B32B17/06C03C17/34
CPCC03C3/093C03C3/085C03C3/087C03C3/091C03C3/095C03C3/097C03C21/005C03C2204/02
Inventor 李毅刚张广军范慧艳乔斯·西默约亨·阿尔克马佩尔
Owner SCHOTT GLASS TECH (SUZHOU) CO LTD
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