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Starch microsphere slow-release fertilizer and preparation method and application thereof

A technology of slow-release fertilizers and starch microspheres, which is applied in application, fertilizer mixtures, fertilization devices, etc., can solve the problems of short fertilizer effect period, weak adsorption capacity, and accelerated soil acidification, so as to achieve prolonged slow-release effect, improved adsorption capacity, The effect of improving the adsorption speed

Active Publication Date: 2014-11-05
力拓肥料(沈阳)有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, traditional chemistry faces two major problems in the process of agricultural production and use: one is the large amount of chemical fertilizers used and the utilization rate is low. In my country, the utilization rate of nitrogen fertilizer in the current season is 30-35%, the utilization rate of phosphorus fertilizer is 10-25%, and the utilization rate of potassium fertilizer is 35%. -50%; Second, the use of chemical fertilizers is unreasonable. At present, the use of quick-acting fertilizers in my country is still dominated by batches of quick-acting fertilizers, which have low utilization rates, short fertilizer cycle, high cost, and pollute the environment.
This method uses sulfur as a raw material, and applying a relatively large amount of elemental sulfur to the soil will affect the soil and accelerate the acidification of the soil; the production equipment is relatively complicated, and solid heat exchangers, coating drums, fluidized beds, and sieves are required. Large-scale equipment such as dividers, and natural beeswax is also added in the preparation process to increase production costs
[0007] Chinese Patent Publication No. CN103708917A discloses a slow-release fertilizer and its preparation method. The method is to dissolve the fertilizer in water and mix it with attapulgite to prepare a slow-release fertilizer, and use the pores in the attapulgite sheet structure to absorb fertilizer nutrients , due to simple physical adsorption, the amount of fertilizer adsorption is limited, and the amount of carrier has a greater impact on the slow-release effect of fertilizers; due to the strong water absorption of attapulgite, the slow-release fertilizer is applied to the soil, attapulgite It quickly absorbs the water in the soil to dissolve the fertilizer, and the nutrients of the fertilizer are released from the pores, which cannot achieve the long-term slow-release effect
However, the disadvantages of native starch such as poor stability, poor dispersibility, and relatively weak adsorption capacity limit its industrial application.

Method used

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  • Starch microsphere slow-release fertilizer and preparation method and application thereof
  • Starch microsphere slow-release fertilizer and preparation method and application thereof
  • Starch microsphere slow-release fertilizer and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] (1) Put 30 parts by weight of urea, 10 parts by weight of ammonium bicarbonate, 10 parts by weight of superphosphate, 10 parts by weight of potassium chloride, 5 parts by weight of trace element fertilizer, and 15 parts by weight of cornstarch into the In the stirred reactor, add 100 parts by weight of distilled water to mix and dissolve, heat at 70°C and stir at a stirring speed of 500r / min, react for 30min, cool to 50°C, and set aside;

[0038] (2) Measure 140 parts by weight of vegetable oil into a vertical emulsifier, add 0.5 parts by weight of emulsifier Span40, heat at 60°C and stir for 1 hour at a stirring speed of 500r / min to completely dissolve it;

[0039] (3) Add the starch solution obtained in step (1) dropwise to the system in step (2), disperse for 1 min at a stirring speed of 10000 r / min, so that the starch droplets are evenly dispersed in the oil phase, and add 0.5 parts by weight of Combined agent epichlorohydrin, stirred at a constant temperature of 50...

Embodiment 2

[0041] (1) Put 20 parts by weight of ammonium sulfate, 10 parts by weight of ammonium nitrate, 10 parts by weight of monoammonium phosphate, 10 parts by weight of diammonium phosphate, 10 parts by weight of potassium sulfate, and 20 parts by weight of tapioca starch into stirring In the mixer, add 120 parts by weight of distilled water to mix and dissolve, heat at 65°C and stir at a stirring speed of 500r / min, react for 40min, cool to 50°C, and set aside;

[0042] (2) Measure 150 parts by weight of cyclohexane into a vertical emulsifier, add 0.5 parts by weight of Span20 and 0.5 parts by weight of Span80, heat at 60°C and stir for 1.5 hours at a stirring speed of 500r / min to dissolve completely;

[0043] (3) Add the starch solution obtained in step (1) dropwise to the system of step (2), and disperse for 1.5 minutes at a stirring speed of 10000r / min, so that the starch droplets are evenly dispersed in the oil phase, and add 0.6 parts by weight of Cross-linking agent epichloro...

Embodiment 3

[0045] (1) 20 parts by weight of sodium nitrate, 10 parts by weight of ammonium nitrate, 20 parts by weight of superphosphate, 10 parts by weight of potassium chloride, 5 parts by weight of potassium monohydrogen phosphate, 15 parts by weight of wheat Starch was put into a stirred reactor, 120 parts by weight of distilled water was added to mix and dissolve, heated at 70°C and stirred at a stirring speed of 500r / min, reacted for 1h, cooled to 50°C, and set aside;

[0046] (2) Measure 140 parts by weight of liquid paraffin into the emulsifier at the bottom of the tank, add 0.5 parts by weight of Tween20 and 0.3 parts by weight of Tween60, heat at 60°C and stir for 2 hours at a stirring speed of 500r / min to completely dissolve it;

[0047] (3) Add the starch solution obtained in step (1) dropwise to the system of step (2), disperse for 2 minutes at a stirring speed of 10000r / min, so that the starch droplets are evenly dispersed in the oil phase, and add 0.8 parts by weight of Co...

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Abstract

The invention provides a starch microsphere slow-release fertilizer and a preparation method thereof. The starch microsphere slow-release fertilizer takes a starch microsphere with characteristics of high adsorption capacity and slow-release dissolution as a slow-release material. The preparation method comprises the following steps of: adding starch to a chemical fertilizer water solution, and stirring and heating for gelatinization; synthesizing the starch microsphere loaded with the fertilizer by adopting a reverse emulsion method. The starch microsphere slow-release fertilizer provided by the invention is made from the biodegradable natural starch, is an excellent carrier type slow-release fertilizer with long nutrient release period, low cost, environmental friendliness and the like and has high market application value.

Description

technical field [0001] The invention belongs to the field of slow-release fertilizers, in particular to a slow-release fertilizer with starch microspheres as a carrier and a preparation method thereof. Background technique [0002] my country is a large agricultural country. With the continuous development of agricultural technology, agricultural production depends more and more on chemical fertilizers. At present, the amount of chemical fertilizers used in my country ranks first in the world, and it shows a trend of increasing year by year. However, traditional chemistry faces two major problems in the process of agricultural production and use: one is the large amount of chemical fertilizers used and the utilization rate is low. In my country, the utilization rate of nitrogen fertilizer in the current season is 30-35%, the utilization rate of phosphorus fertilizer is 10-25%, and the utilization rate of potassium fertilizer is 35%. -50%; Second, the use of chemical fertilize...

Claims

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Application Information

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IPC IPC(8): C05G3/00C05G3/08C05G3/90
Inventor 陈庆孙丽枝
Owner 力拓肥料(沈阳)有限公司
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