Boron nitride ceramic side seal plate for thin strip continuous casting and preparation method thereof
A technology of boron nitride and side sealing plates, which is applied in the field of continuous casting of iron and steel, can solve the problems of uniform phase composition and microstructure of side sealing plates, thermal expansion mismatch of side sealing plates, and easy generation of cold blocks on side sealing plates, etc. It achieves the effects of excellent corrosion resistance to molten steel, good thermal shock resistance, and improved service life
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Embodiment 1
[0026] Step 1: Mix hexagonal boron nitride powder, aluminum nitride powder, magnesium aluminum spinel powder, mullite powder, MgAlON powder, AlON powder and CaAl 4 o 7 The powders were milled for 24 hours with a ball mill using a wet ball milling method. The ball milling solvent in the ball milling process was absolute ethanol. The purity of the above-mentioned raw materials must reach the level of analytical purity. During the above-mentioned ball milling process, the hexagonal boron nitride slurry, nitrogen Aluminum paste, magnesium aluminum spinel paste, mullite paste, MgAlON paste, AlON paste, CaAl 4 o 7 The particle size of the solid particles in the slurry is 2 μm, and then the above slurry is dried to form the corresponding powder;
[0027] Step 2: Calculated by mass percentage: 70% hexagonal boron nitride, 10% aluminum nitride powder, 5% magnesium aluminum spinel, 5% mullite, 5% MgAlON, 3% AlON, CaAl 4 o 7 2% Select the powder after the drying treatment in step 1, ...
Embodiment 2
[0036] Step 1: Mix hexagonal boron nitride powder, aluminum nitride powder, magnesium aluminum spinel powder, mullite powder, MgAlON powder, CaZrO 3 Powder and CaTiO 3 The powders were ball milled for 36 hours with a ball mill using wet ball milling. The ball milling solvent in the ball milling process was acetone. Slurry, Magnesium Aluminum Spinel Slurry, Mullite Slurry, MgAlON Slurry, CaZrO 3 Slurry and CaTiO 3 The particle size of the solid particles in the slurry is 4 μm, and then the above slurry is dried to form the corresponding powder;
[0037] Step 2: Calculated by mass percentage: 60% of hexagonal boron nitride, 15% of aluminum nitride powder, 10% of magnesium aluminum spinel, 10% of mullite, 2% of MgAlON, CaZrO 3 2% and CaTiO 3 1% Select the powder after the drying treatment in step 1, and carry out the wet ball milling and mixing treatment on the above powder through a ball mill. The time of the wet ball milling mixing treatment is 24 hours, until the mixture i...
Embodiment 3
[0046] Step 1: Mix hexagonal boron nitride powder, aluminum nitride powder, magnesium aluminum spinel powder, mullite powder, AlON powder, CaAl 4 o 7 Powder, CaZrO 3 Powder and CaTiO 3 The powders were milled for 36 hours with a ball mill using a wet ball milling method. The ball milling solvent in the ball milling process was technical alcohol with a purity of more than 95%. Boron slurry, aluminum nitride slurry, magnesium aluminum spinel slurry, mullite slurry, AlON slurry, CaAl 4 o 7 Slurry, CaZrO 3 Slurry and CaTiO 3 The particle size of the solid particles in the slurry is 6 μm, and then the above slurry is dried to form the corresponding powder;
[0047]Step 2: Calculated by mass percentage: 30% hexagonal boron nitride, 30% aluminum nitride, 20% magnesium aluminum spinel, 10% mullite, 5% AlON, CaAl 4 o 7 2%, CaZrO 3 2% and CaTiO 3 1%, select the powder after the drying treatment in step 1, and carry out the wet ball milling mixing process on the above powder th...
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