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Modified guanidine gum fracturing fluid as well as preparation method and application thereof

A guar gum fracturing fluid and fracturing fluid technology, applied in the field of modified guar gum fracturing fluid and its preparation, can solve problems that have not been reported, and achieve strong on-site operability, self-agglomeration, and simple dispersion methods Effect

Inactive Publication Date: 2014-05-21
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, the dispersion method of nanomaterials in the modified guar gum fracturing fluid system and the application of nanomaterials in the modified guar gum fracturing fluid system have not been reported in China.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Contains Nano MgC 2 o 4 The preparation method of the modified guar gum fracturing fluid: the self-made nano-MgC 2 o 4 Add the powder into glycerin, stir it magnetically for 30 minutes, then add 50ml of modified guar gum fracturing fluid aqueous solution, and continue stirring for 30 minutes to obtain nano-MgC with good dispersibility. 2 o 4 Association modified guar gum fracturing fluid system. The nano-MgC 2 o 4 The particle size is 11.8nm, and the specific surface area is 88.33m 2 / g.

Embodiment 2

[0025] Contains nano Al(OH) 3 The preparation method of the modified guar gum fracturing fluid: the self-made nano-Al(OH) 3 Add in glycerol, stir magnetically for 30 minutes, then add 50ml of guar gum aqueous solution, continue stirring for 30 minutes to obtain nano Al(OH) with good dispersibility 3 Association modified guar gum fracturing fluid system. The nano-Al(OH) 3 The particle size is 37.8nm and the specific surface area is 9.59m 2 / g.

Embodiment 3

[0027] Contains nano γ-Al 2 o 3 The preparation method of the modified guar gum fracturing fluid: the self-made nano-Al(OH) 3 Add it into glycerol, stir it magnetically for 30 minutes, then add 50ml of guar gum aqueous solution, and continue stirring for 30 minutes to obtain nanometer γ-Al2O with good dispersibility 3 Association modified guar gum fracturing fluid system. The nano-γ-Al 2 o 3 The particle size is 18.7nm, and the specific surface area is 370.49m 2 / g.

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Abstract

The invention relates to a modified guanidine gum fracturing fluid as well as a preparation method and an application thereof. The fracturing fluid contains nano materials, wherein the nano materials comprise MgC2O4, Al(OH)3, gamma-Al2O3, SiO2, TiO2 and ZnO; the particle sizes of the nano materials are 1-100nm; the specific surface area is 9-550m<2> / g; the guanidine gum is hydroxypropyl (HPG) and carboxymethyl hydroxypropyl (CMHPG); and the mass fraction is 0.1-1.5%. The adopted nano materials and dispersing aids are nontoxic and environment-friendly materials, secondary pollution is not caused, the nano materials are dispersed into the dispersing aids in advance, transportation and operation of superfine nano powder materials applied to an oil field are facilitated, the dispersing method is simple, and strong in field operability, has a broad application prospect in fracturing production stimulation of a high-temperature deep well in exploration and development of low-permeability oil and gas fields.

Description

technical field [0001] The invention relates to the field of guar gum fracturing fluid, in particular to a modified guar gum fracturing fluid containing nanomaterials and a preparation method and application thereof. Background technique [0002] Fracturing fluid is the liquid used in the process of reservoir stimulation and stimulation. A fracturing fluid with good performance should meet the following requirements: high viscosity, low friction, low fluid loss, no damage to the formation, wide source of raw materials, low cost, and simple preparation, etc. [0003] Guar gum polymer molecules are rich in hydroxyl groups, have good water solubility and cross-linking properties, and are widely used as fracturing thickeners in oil and gas fields at home and abroad. The application ratio of guar gum fracturing fluid system is over 90%. [0004] However, in recent years, guar gum resources in the international market have become tighter, and prices have continued to rise sharpl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/68
CPCC09K8/665C09K8/68C09K8/90C09K2208/10
Inventor 王宝峰黄静蒋廷学张保平陈作卫然徐胜强魏娟明刘建坤
Owner CHINA PETROLEUM & CHEM CORP
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