Multi-reflection-band layered cholesteric liquid crystal composite film with light response character and process
A technology of cholesteric liquid crystal and composite film, which can be used in optics, nonlinear optics, instruments, etc., and can solve problems such as limited applications
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Embodiment 1
[0026] The composition and chirality of the layered cholesteric liquid crystal of the film are respectively (both percentages):
[0027] Layer I: SLC1717 / C6M / S811 / Irg651=54.0 / 30.0 / 15.0 / 1.0, left-handed;
[0028] Layer II: SLC1717 / CD1=94.0 / 6.0, right-handed;
[0029] Layer III: SLC1717 / C6M / S811 / Irg651=54.0 / 30.0 / 15.0 / 1.0, left-handed.
[0030] SLC1717 is a small molecule N mixed crystal (n o = 1.519, n e = 1.720, Δn = n e -n o = 0.201, T N-I =92 o C), the structures of C6M, S811, Irg651 and CD1 are shown in Table 1.
[0031] The selective reflection wavelength of the cholesteric liquid crystal prepared in layer II can be changed under the irradiation of light, figure 2 This property is briefly described. The composition (mass ratio) of the cholesteric liquid crystal configured here is SLC1717 / CD1=95.0 / 5.0, it can be found that the cholesteric liquid crystal is at 2 mW / cm 2 , under the irradiation of 365 nm ultraviolet light, its reflection wavelength can be red-sh...
Embodiment 2
[0046] The composition and chirality of the layered cholesteric liquid crystal of the film are respectively (both percentages):
[0047] Layer I: SLC1717 / C6M / S811 / Irg651=54.0 / 30.0 / 15.0 / 1.0, left-handed;
[0048]Layer II: SLC1717 / CD1=94.0 / 6.0, right-handed;
[0049] Layer III: SLC1717 / C6M / R811 / Irg651=59.0 / 30.0 / 10.0 / 1.0, right-handed.
[0050] The sample preparation process is as in Example 1.
[0051] Then the film made has the following characteristics (such as Figure 4 shown):
[0052] (1) Initially, the film has two distinct reflection bands, one at 700 nm and one at 1020 nm, which are the reflection bands of layer I and layer III respectively; while the reflection band of layer II is calculated according to the helical twisting force of CD1 It can be seen that at 455 nm, the reflection band is covered by the absorption of CD1;
[0053] (2) at 1 mW / cm 2 Under the irradiation of 365 nm, after 130 s, the reflection band of layer II coincides with the reflection band of ...
Embodiment 3
[0060] The composition and chirality of the layered cholesteric liquid crystal of the film are respectively (both percentages):
[0061] Layer I: SLC1717 / C6M / S811 / Irg651=54.0 / 30.0 / 15.0 / 1.0, left-handed;
[0062] Layer II: SLC1717 / CD1=94.0 / 6.0, right-handed;
[0063] Layer III: SLC1717 / C6M / S811 / Irg651=59.0 / 30.0 / 10.0 / 1.0, left-handed.
[0064] The sample preparation process is as in Example 1.
[0065] Then the film made has the following characteristics (such as Figure 5 shown):
[0066] (1) Initially, the film has two distinct reflection bands, one at 700 nm and one at 1020 nm, which are the reflection bands of layer I and layer III respectively; while the reflection band of layer II is calculated according to the helical twisting force of CD1 It can be seen that at 455 nm, the reflection band is covered by the absorption of CD1;
[0067] (2) with 1 mW / cm 2 After irradiating at 365 nm for 100 s and 220 s, the reflection bands of layer II coincide with those of layer I a...
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