Adamantyl benzocyclobutene monomer and synthesizing method of polymer of adamantyl benzocyclobutene monomer

A technology of adamantyl benzene and benzocyclobutene, which is applied in chemical instruments and methods, compounds of elements of Group 4/14 of the periodic table, organic chemistry, etc., can solve problems such as low dielectric constant

Active Publication Date: 2014-03-26
FUDAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] However, the dielectric constant of the current benzocyclobutene-based polymers is not low enough, and its hydrophobicity and heat resistance need to be further improved.

Method used

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  • Adamantyl benzocyclobutene monomer and synthesizing method of polymer of adamantyl benzocyclobutene monomer
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  • Adamantyl benzocyclobutene monomer and synthesizing method of polymer of adamantyl benzocyclobutene monomer

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Embodiment Construction

[0076] In order to make the object, technical solution and advantages of the present invention clearer, various embodiments of the present invention will be described in detail below in conjunction with the accompanying drawings. However, those of ordinary skill in the art can understand that, in each implementation manner of the present invention, many technical details are provided for readers to better understand the present application. However, even without these technical details and various changes and modifications based on the following implementation modes, the technical solution claimed in each claim of the present application can be realized.

[0077] The first embodiment of the present invention relates to an adamantyl benzocyclobutene monomer, the specific structural formula is

[0078]

[0079] in, For adamantane, is benzocyclobutene, O is oxygen, Si is silicon; m and n are the number of substituent groups on the 1, 3, 5, and 7 positions of adamantane, th...

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Abstract

The invention relates to a high molecular material and discloses an adamantyl benzocyclobutene monomer and a synthesizing method of a polymer of the adamantyl benzocyclobutene monomer. According to the adamantyl benzocyclobutene monomer and the synthesizing method of the polymer of the adamantyl benzocyclobutene monomer, the structural formula of the adamantyl benzocyclobutene monomer is shown as the specification, wherein a formula in the specification is adamantane; a formula in the specification is benzocyclobutene; O is oxygen and Si is silicon; m and n are the quantities of substituent groups on 1, 3, 5 and 7 sites of the adamantane; the sum of the m and the n is smaller than or equal to 4; the n is more than or equal to 1 and less than or equal to 4; R1 is a first fat substituent group or a first aromatic substituent group; R2 is a second fat substituent group or a second aromatic substituent group; R3 is a third fat substituent group or a third aromatic substituent group. The adamantyl benzocyclobutene monomer prepared by the invention is used for carrying out a polymerization reaction to obtain an adamantyl benzocyclobutene monomer polymer. According to the adamantyl benzocyclobutene monomer and the synthesizing method of the polymer of the adamantyl benzocyclobutene monomer, the adamantyl benzocyclobutene monomer and the polymer thereof have low dielectric constants and low dielectric losses; the dielectric properties are good; meanwhile, the adamantyl benzocyclobutene monomer and the polymer thereof have higher hydrophobic property and heat resistance.

Description

technical field [0001] The invention relates to polymer materials, in particular to a synthesis method of benzocyclobutene monomers containing adamantane groups and polymers thereof. Background technique [0002] With the development of electronic science, high-performance polymer materials have an increasingly broad market, among which polymer materials with high heat resistance, low water absorption, and low dielectric constant can be used for interlayer dielectrics, substrate materials, bottom Filling materials, etc., are widely used in microelectronic packaging and aerospace industries. At present, in the field of electronic packaging, with the development of large-scale and ultra-large-scale integrated circuits, the influence of dielectric properties (permittivity ε and dielectric loss factor tanδ) on the substrate is very important. As high-frequency substrate technology and products occupy an increasingly important position, the development of high-frequency circuit ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F7/18C08F130/08
Inventor 程元荣孔令强肖斐
Owner FUDAN UNIV
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