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Low-foam middle-cloud-point environment-friendly water base metal cleaner composition and preparing method thereof

A cleaning agent and base metal technology, applied in the field of metal cleaning agents, can solve the problems of poor water solubility, low cloud point temperature of surfactants, and limited application range.

Inactive Publication Date: 2014-01-01
BOER TECH WUHAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Nonionic surfactants have low foaming properties, but their use is limited due to their low cloud point and poor water solubility; and the amount of defoamers is limited due to the impact of defoaming mechanisms and economic costs, so how to improve these two factors is to achieve The key to low-foaming properties and affordability
In addition, appropriately increasing the cleaning temperature can also improve the cleaning rate of metals, but the cloud point temperature of the new non-ionic low-foaming surfactants is generally low. At room temperature, its aqueous solution becomes turbid, and the surfactant precipitates out, losing its cleaning effect.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Embodiment 1: A kind of low foam medium cloud point environment-friendly water-based metal cleaning agent

[0035] According to the composition raw material formula of above-mentioned mass percentage, take and prepare various raw materials respectively, prepare cleaning agent:

[0036] 1) Weigh 10.0 g of solid-phase raw materials benzotriazole, 80.0 g of disodium ethylenediamine tetraacetate, 40.0 g of sodium carbonate, and 10.0 g of sodium hydroxide according to the dosage of the formula, and add them to the preparation container in sequence;

[0037] 2) Weigh 10.0g of liquid-phase raw material triethanolamine oleic acid soap, 2.5g of low-foaming and low cloud point nonionic surfactant “DF-12”, 2.5g of commercial “FK-86” and low-foaming anionic Surfactant product "NF-10" 12.5g, product "H66" 15.0g, antirust agent triethanolamine 150.0g, antifoaming agent polyether product "L61" 7.5g, add to the preparation container of the above step 1) in sequence ;

[0038] 3) Fina...

Embodiment 2

[0040] Embodiment 2: a kind of environment-friendly water-based metal cleaning agent with low foam and medium cloud point,

[0041] According to the composition raw material formula of above-mentioned mass percentage, take and prepare various raw materials respectively, prepare cleaning agent:

[0042] 1) Weigh 15.0 g of solid-phase raw materials benzotriazole, 60.0 g of disodium ethylenediamine tetraacetate, 20.0 g of sodium carbonate, and 7.0 g of sodium hydroxide according to the dosage of the formula, and add them to the preparation container in sequence;

[0043] 2) Weigh 10.0g of liquid-phase raw material triethanolamine oleic acid soap, 2.5g of low-foaming and low cloud point nonionic surfactant “DF-12”, 2.5g of commercial “FK-86” and low-foaming anionic Surfactant product "NF-10" 2.5g, product "H66" 20.0g, antirust agent triethanolamine 120.0g, antifoaming agent polyether product "L61" 7.5g, add to the preparation container of the above step 1) in sequence .

[0044]...

Embodiment 3

[0046] Embodiment 3: A kind of low foam medium cloud point environment-friendly water-based metal cleaning agent

[0047] According to the composition raw material formula of above-mentioned mass percentage, take and prepare various raw materials respectively, prepare cleaning agent:

[0048] 1) Weigh 10.0 g of solid-phase raw materials benzotriazole, 80.0 g of disodium ethylenediamine tetraacetate, 20.0 g of sodium carbonate, and 10.0 g of sodium hydroxide according to the dosage of the formula, and add them to the preparation container in sequence;

[0049] 2) Weigh 5.0g of liquid-phase raw materials triethanolamine oleic acid soap, 2.5g of low-foaming and low cloud point nonionic surfactant “DF-12”, 5.0g of commercial “FK-86” and low-foaming anionic Surfactant product "NF-10" 10.0g, product "H66" 20.0g, antirust agent triethanolamine 100.0g, antifoaming agent polyether product "L61" 7.5g, add to the preparation container of the above step 1) in sequence

[0050]3) Finally,...

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PUM

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Abstract

The invention provides a low-foam middle-cloud-point environment-friendly water base metal cleaner composition and a preparing method thereof, and belongs to the field of metal cleaners. The low-foam middle-cloud-point environment-friendly water base metal cleaner composition is composed of low-foam low-cloud-point nonionic surface active agents, low-foam anion surface active agents, triethanolamine oleic soap, triethanolamine, styrene acrylic three azole nitrogen, ethylene diamine tetraacetic acid, sodium carbonate, polyether, organosilicone, sodium hydroxide and deionized water, wherein solid-phase raw material and liquid-phase raw material are sequentially added to a reaction container according to a formulation and metering, the organosilicone and the deionized water are finally added to the reaction container, stirring is conducted for 10min to 20min under the condition of indoor temperature, and clear products with a pH value ranging from 9 to 10 are obtained. The triethanolamine oleic soap is a cloud point improving agent, good water solubility is achieved after the triethanolamine oleic soap and the triethanolamine are re-compounded according to the ratio, solubilizing ability of the low-foam low-cloud-point nonionic surface active agents is enhanced, therefore the temperature of the solution cloud point of the cleaner is improved to 45 DEG C, cleaning efficiency of the cleaner is improved, and the low-foam middle-cloud-point environment-friendly water base metal cleaner particularly suitable for high-pressure spraying cleaning is obtained.

Description

technical field [0001] The invention relates to a low-foaming, medium-cloud point, environment-friendly water-based metal cleaning agent composition and a preparation method thereof, belonging to the field of metal cleaning agents. Background technique [0002] At present, there are many kinds of ordinary water-based metal cleaning agents on the market, which basically belong to high-foaming cleaning agents for soaking and spray cleaning. During spray cleaning, too much foam and too long defoaming time will not only hinder the cleaning of dirt on the metal surface, but also easily produce residues of cleaning agents, which will ultimately affect the cleaning effect. On the other hand, the overflow of high foam will also affect the cleaning operation. Therefore, the market has put forward higher and higher requirements for the comprehensive performance and service conditions of cleaning agents. Improving the cleaning rate of metal can be achieved by changing the cleaning co...

Claims

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Application Information

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IPC IPC(8): C23G1/18
Inventor 胡金霞余文雅江晓炯
Owner BOER TECH WUHAN
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