High-strength cold-rolled steel plate and manufacturing method thereof
A technology of cold-rolled steel sheet and manufacturing method, applied in the field of cold-rolled steel sheet and its manufacturing, capable of solving problems such as insufficient corrosion resistance and poor surface appearance of cold-rolled steel sheet
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Embodiment 1
[0161] Using a cold-rolled steel sheet containing 1.2% by mass Si and 2.0% by mass Mn, degreasing, annealing, and pickling were performed under the following conditions to obtain steel sheets with different precipitation forms of Si-containing oxides.
example 1
[0163] Degreasing: immerse in 5% (mass %, hereinafter the same for aqueous solution) sodium hydroxide aqueous solution at 60°C for 30 seconds → wash with water → dry
[0164] Annealing: 3% hydrogen-containing inert gas environment, dew point -20°C, heating at 870°C×200s
[0165] Pickling; immerse in 3% hydrochloric acid aqueous solution at 60°C for 5 seconds → wash with water → dry
[0166] (Example 2 of the present invention)
[0167] Degreasing: Soak in 5% sodium hydroxide aqueous solution at 60°C for 30 seconds → wash with water → dry
[0168] Annealing: 3% hydrogen-containing inert gas environment, dew point -15°C, heating at 870°C×200s
[0169] Pickling; immerse in 3% hydrochloric acid aqueous solution at 60°C for 5 seconds → wash with water → dry
Embodiment 2
[0190] Using a cold-rolled steel sheet containing 1.5% by mass of Si and 1.8% by mass of Mn, it was degreased by immersing it in a 5% sodium hydroxide aqueous solution at 60°C for 30 seconds, washed with water, and dried. After that, as shown in Table 2 , annealed at 840°C for 120 seconds in a 3% hydrogen-containing inert gas environment with different dew points, and then pickled with 3% hydrochloric acid aqueous solution at 60°C for 5 seconds, washed with water, and dried to prepare the test material.
[0191] These test materials were cut in a direction perpendicular to the surface of the steel plate, and the cross-section including the vicinity of the surface was observed by TEM in the same manner as in Example 1 above. That is, for each test material, five samples including samples for TEM observation with a steel plate surface length of 10 μm or more were prepared, observed at a magnification of 60,000, and the amount of Si-containing oxide in the steel plate surface leng...
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