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Method for preparing ordered porous energetic crystal material

A crystal material and crystal technology, which is applied in the field of preparation of ordered porous energetic crystal materials, can solve the problems of not obtaining ordered porous energetic materials, and achieve the effects of easy control of reaction conditions, simple process flow and mild reaction conditions

Active Publication Date: 2015-03-04
INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the above studies only apply porous structure materials to energetic materials, and use ordered porous structure materials as carrier materials to combine with energetic materials. Porous materials themselves are not energetic materials. A kind of ordered porous composite energetic material, and the ordered porous energetic material composed of the energetic material itself has not been obtained

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  • Method for preparing ordered porous energetic crystal material
  • Method for preparing ordered porous energetic crystal material
  • Method for preparing ordered porous energetic crystal material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The preparation method steps of ordered porous CL-20 are as follows:

[0027] Take 0.1g of CL-20 at room temperature and dissolve it in 5ml of nitrogen-nitrogen dimethylformamide under the condition of magnetic stirring at a speed of 500 rpm, and stir until CL-20 is completely dissolved.

[0028] Take 0.05g of calix[4]arene and add it into the solution, and continue stirring until the calix[4]arene is completely dissolved.

[0029] Under the condition of stirring, add the solution dropwise to 50ml double distilled water, and the CL-20 / cup[4]arene compound slowly precipitates out. Stirring was continued for 30 minutes, filtered, and vacuum-dried at 50° C. for 12 hours to obtain CL-20 / calix[4]arene complex.

[0030] Take 0.1g of CL-20 / cup[4]arene compound and put it into 100ml double distilled water, wash it under magnetic stirring at 100rpm, so that the calix[4]arene compound in the compound is slowly dissolved, and repeat the washing several times to remove Calix[4]ar...

Embodiment 2

[0033] The preparation method steps of ordered porous CL-20 are as follows:

[0034] Take 0.1g of CL-20 at room temperature and dissolve it in 5ml of nitrogen-nitrogen dimethylformamide under the condition of magnetic stirring at a speed of 500 rpm, and stir until CL-20 is completely dissolved.

[0035] Add 0.05g of β-cyclodextrin into the solution and continue stirring until the β-cyclodextrin is completely dissolved.

[0036] Under the condition of stirring, add the solution dropwise into 50ml double-distilled water, the CL-20 / β-cyclodextrin complex slowly precipitates, continue to stir for 30 minutes, filter, and vacuum dry at 50°C for 12h to obtain CL-20 / β-cyclodextrin complex β-cyclodextrin complex.

[0037] Take 0.1g of CL-20 / β-cyclodextrin complex and put it into 100ml double-distilled water, and wash it under magnetic stirring at 100rpm to slowly dissolve the β-cyclodextrin in the complex, and repeat the washing several times to remove β-cyclodextrin in CL-20 / β-cyclo...

Embodiment 3

[0039] The preparation method steps of ordered porous HMX are as follows:

[0040] At room temperature, 0.1 g of HMX was dissolved in 5 ml of nitrogen-nitrogen dimethylformamide under magnetic stirring at a speed of 500 rpm, and stirred until the HMX was completely dissolved.

[0041] Take 0.05g of calix[8]arene and add it into the solution, and continue stirring until the calix[8]arene is completely dissolved.

[0042] Under the condition of stirring, add the solution dropwise to 50ml double-distilled water, CL-20 / cup[8]arene complex slowly precipitates, continue to stir for 30 minutes, filter, and vacuum dry at 50°C for 12h to obtain HMX / cup[8] 8] Aromatic Complex.

[0043]Take 0.1g of HMX / calix[8]arene complex and put it into 100ml double distilled water, wash it under magnetic stirring at 100rpm to slowly dissolve the calix[8]arene in the compound, repeat the washing several times to remove HMX Calix[8]arene in a calix[8]arene complex, filtered, and dried to give ordered...

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Abstract

The invention discloses a method for preparing an ordered porous energetic crystal material. The method comprises the following steps of: dissolving a certain amount of energetic materials in a good solvent at room temperature; adding a certain amount of crystal morphology control agents into the solution in the previous step, stirring, dissolving, and slowly adding the solution in the previous step into a poor solvent of the energetic materials and the crystal morphology control agents under the magnetic stirring conditions; continuously stirring the solution in the previous step for a certain time, filtering, and obtaining a composite material of the energetic materials and the crystal morphology control agents; adding the obtained composite material into the solvent, wherein the solvent is a poor solvent of the energetic materials and a good solvent of the crystal morphology control agents; repeatedly washing and removing the crystal morphology control agents; and drying to obtain pure ordered porous energetic crystal material. The preparation method is simple in process flow and mild in reaction conditions and suitable for various energetic materials, the reaction conditions are easy to control, and the prepared ordered porous energetic crystal material has the purity of over 99.5 percent.

Description

technical field [0001] The invention belongs to the field of energetic materials, and in particular relates to a preparation method of an ordered porous energetic crystal material. Background technique [0002] Ordered porous material is a new type of nanostructured material that emerged rapidly in the 1990s. It has been highly valued by the international physics, chemistry and materials science circles since its birth, and has rapidly developed into one of the interdisciplinary research hotspots. Ordered porous materials have the characteristics of uniform pore size, orderly arrangement, and continuous adjustment of pore diameter within a certain range. etc. have broad application prospects. Therefore, the application of porous materials in the research of energetic materials will definitely expand and deepen the research of energetic materials. [0003] Energetic materials, mainly including explosives, propellants, and pyrotechnic agents, are multifunctional materials th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C06B21/00C06B23/00C06B25/34C06B25/32
Inventor 沈金朋杨光成谯志强李瑞
Owner INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS
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