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Clarification method of alumina silicate glass melts

A technology of aluminosilicate glass and sulfate, which is applied in glass production, glass furnace equipment, glass manufacturing equipment, etc., can solve the problems that it is difficult to fully meet the production and preparation requirements, and the tiny bubbles are difficult to overflow, so as to optimize the clarification effect and promote The effect of clarifying the quality and prolonging the clarifying time

Inactive Publication Date: 2013-03-20
(CNBM) BENGBU DESIGN & RES INST FOR GLASS IND CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Atmospheric pressure clarification is basically used in the current float glass industry, which can meet the clarification technical requirements of ordinary glass. However, for the reality that tiny bubbles are difficult to overflow during the preparation of special glass, normal pressure clarification is difficult to fully meet the production and preparation requirements.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Divided into two groups: Invention Group 1 and Control Group 1. The production conditions of the two groups are completely the same except for the clarifying agent used and the pressure of the clarifying part. The composite clarifying agent used in Invention Group 1 accounts for the mass percentage of the glass batch For: K 2 SO 4 0.5%, Na 2 SO 4 3.6%, SnO 2 0.3%, CeO 2 0.2%, the clarification part pressure is 9×10 4 Pa, the number of bubbles per unit volume of produced aluminosilicate glass is 22 / cubic centimeter, control group 1 adopts existing clarifying agent and clarification method to produce aluminosilicate glass, other conditions are exactly the same as invention group 1, produces aluminum The number of bubbles per unit volume of the silicate glass is 36 per cubic centimeter, and the elastic modulus and Mohs hardness of the aluminosilicate glass produced by the invention group 1 and the control group 1 are basically the same.

Embodiment 2

[0024] Divided into two groups, the invention group 2 and the control group 2, the production conditions of the two groups are completely the same except for the clarifying agent used and the pressure of the clarifying part. For: K 2 SO 4 0.4%, Na 2 SO 4 1%, Li 2 SO 4 0.3%, NaNO 3 1%, SnO 2 0.3%, Sb 2 o 3 0.2%, the clarification part pressure is 1×10 4 Pa, the number of bubbles per unit volume of produced aluminosilicate glass is 18 / cubic centimeter, the control group 2 adopts existing clarifying agent and clarification method to produce aluminosilicate glass, other conditions are exactly the same as the invention group 2, produces aluminum The number of bubbles per unit volume of the silicate glass is 42 per cubic centimeter, and the elastic modulus and Mohs hardness of the aluminosilicate glass produced by the invention group 2 and the control group 2 are basically the same.

Embodiment 3

[0026] Divided into two groups, the invention group 3 and the control group 3, the production conditions of the two groups are completely the same except for the clarifying agent used and the pressure of the clarifying part. For: K 2 SO4 0.9%, Na 2 SO 4 2%, KNO 3 1%, SnO 2 0.3%, CeO 2 0.3%, the clarification part pressure is 1×10 3 Pa, the number of bubbles per unit volume of produced aluminosilicate glass is 9 / cubic centimeter, control group 3 adopts existing clarifier and clarification method to produce aluminosilicate glass, other conditions are exactly the same as invention group 3, produces aluminum The number of bubbles per unit volume of the silicate glass is 51 per cubic centimeter, and the elastic modulus and Mohs hardness of the aluminosilicate glass produced by the invention group 3 and the control group 3 are basically the same.

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Abstract

The invention discloses a clarification method of alumina silicate glass melts. The method comprises physical treatment and chemical treatment to the alumina silicate glass melts, wherein the physical treatment is to control the air pressure of clarifying parts of the alumina silicate glass melts to 100 to 9*10<4>Pa; and the chemical treatment is to add a composite clarifying agent to the alumina silicate glass mixture, wherein the composite clarifying agent is the composition formed by mixing two or more than two of sulfate or / and nitrate of K, sulfate or / and nitrate of Na and sulfate or / and nitrate of Li with two or more than two of Sn oxide, Sb oxide and Ce oxide. According to the clarification method, the composite clarifying agent is adopted and realizes gradient chemical clarification under different temperatures, so that the clarifying agent in the glass melts can be molten at different temperature ranges during melting, and gas is continuously generated by the glass melts, and the clarifying time of the glass melts is prolonged; and the physical clarifying way under reduced pressure is adopted while the chemical clarifying way is carried out, so that the bubble can be faster generated and overflowed, and the clarifying effect of the high-viscosity alumina silicate glass can be optimized.

Description

technical field [0001] The invention belongs to the field of glass manufacturing, specifically a clarification method for aluminosilicate glass, which improves the growth and overflow rate of bubbles in the melting process of glass liquid, thereby improving the clarification quality of glass liquid and improving the performance index of glass original sheets . Background technique [0002] In the past ten years, the electronic information industry has developed by leaps and bounds. Portable electronic devices such as mobile phones, notebook computers and even tablet computers have entered people's lives more and more, bringing convenience to human production and life. No matter how different the functions of these electronic devices are, it is inevitable to use glass as the main component of the display system. The traditionally used soda-lime-silica glass has poor mechanical strength and wear resistance, and cannot be used for a long time and in Use in special circumstance...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03B5/225
CPCC03B5/2252C03C1/004Y02P40/57
Inventor 彭寿曹欣马立云王芸吴飞宋在芝石丽芬崔介东钱学君
Owner (CNBM) BENGBU DESIGN & RES INST FOR GLASS IND CO LTD
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