Method for comprehensively using vanadium-titanium magnetite by shaft furnace reduction and electric furnace melting
A vanadium-titanium magnetite and electric furnace technology, applied in electric furnaces, shaft furnaces, furnaces, etc., can solve the problems of rapid temperature drop, high pressure, and unfavorable reactions of reducing gas, and achieve the effect of alleviating the increasingly tense
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Embodiment 1
[0039] Example 1: The vanadium-titanium magnetite concentrate (TFe 43.2%, FeO 16.8%, V2O 51.2%, TiO2 1.6%) with a particle size of -0.074mm accounting for 60% is mixed with a binder to make 10-15mm pellets are dried at 200°C for 2 hours, roasted at 1100°C for 3 hours, then loaded into a shaft furnace, and reduced in a shaft furnace at 1100°C for 4.5 hours, wherein the pressure of the reducing gas is 0.3 MPa, and the H2+CO in the reducing gas ≈92%, and the molar ratio of H2 to CO is 2.8. The direct reduction product is put into an electric furnace for melting and separation. The melting temperature is 1650°C. The analysis of the molten iron element is TFe94.8%, V2O50.2%, TiO20.06%, and the molten slag element analysis is TFe5%, V2O52.8 %, TiO2 54.4%. From vanadium-titanium magnetite concentrate to smelting stage, the recovery rates of iron, vanadium and titanium are 95%, 92% and 99% respectively.
Embodiment 2
[0040] Example 2: The vanadium-titanium magnetite concentrate (TFe 55.9%, FeO 22.8%, V2O50.53%, TiO2 11.8%) with a particle size of -0.074mm accounting for 75% was added to the binder and mixed evenly to produce 10-15mm pellets were dried at 200°C for 2 hours, roasted at 1100°C for 3 hours, then loaded into a shaft furnace, and reduced in a shaft furnace at 1050°C for 5.5 hours, wherein the pressure of the reducing gas was 0.2 MPa, and H2+CO in the reducing gas ≈90%, and the molar ratio of H2 to CO is 1.6. The direct reduction product is put into an electric furnace for melting and separation. The melting temperature is 1550°C. The analysis of molten iron elements is TFe94%, V2O5 0.1%, TiO2 0.05%, and the analysis of molten slag elements is TFe 9%, V2O5 2.2%, and TiO2 52.7%. . From vanadium-titanium magnetite concentrate to smelting stage, the recovery rates of iron, vanadium and titanium are 97%, 91% and 99% respectively.
[0041] Beneficial effects of the present invention...
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