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Fully-degradable mulching film capable of applying fertilizer, and preparation method for fully-degradable mulching film

A fully degradable and mulching technology, applied in fertilization devices, fertilizer mixtures, applications, etc., can solve problems such as inability to absorb and utilize crops, secondary environmental pollution, and decline in cultivated land quality, so as to maintain full biodegradability and improve processability , The effect of increasing the interface binding force

Inactive Publication Date: 2013-01-16
WUHAN HUALI ENVIRONMENT PROTECTION SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] While plastic film mulching technology has brought huge benefits to my country's agricultural production increase, it has also brought serious pollution to the soil, and there is a potential danger of white pollution.
Since most of the mulch films currently used are polyethylene or polyvinyl chloride mulch films, the stability of this type of mulch film is extremely high, and the fragments left in the soil cannot be degraded by soil microorganisms, nor can they be absorbed and utilized by crops.
A large number of plastic film residues have brought serious negative impacts on the ecological environment of farmland and agricultural production, causing a series of problems such as soil structure damage, arable land quality decline, crop production reduction, agricultural operation obstruction, and secondary environmental pollution.
In addition, the crops covered with plastic film need to manually pierce the plastic film to drip-irrigate the crops during the growth period, which consumes a lot of manpower and material resources, and also increases the number of broken films, which makes it difficult to recover the plastic film later.

Method used

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  • Fully-degradable mulching film capable of applying fertilizer, and preparation method for fully-degradable mulching film
  • Fully-degradable mulching film capable of applying fertilizer, and preparation method for fully-degradable mulching film
  • Fully-degradable mulching film capable of applying fertilizer, and preparation method for fully-degradable mulching film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] First dissolve the polyvinyl alcohol in hot glycerol under stirring conditions, then disperse the pulverized ammonium sulfate powder into the polyvinyl alcohol glycerol solution, and then spray the mixture into an inert hot air flow to make droplets Shrink it into a spherical shape and then dry to obtain ammonium sulfate microcapsules.

[0032] 30 parts by mass of PBAT, 10 parts by mass of polylactic acid, 30 parts by mass of corn starch, 10 parts by mass of glycerol, 2 parts by mass of BASF chain extender JONCRYL ADR-4368, 8 parts by mass of ammonium sulfate microcapsules and 10 parts by mass of light The calcium carbonate is mixed uniformly in a high-speed mixer, and then the mixture is mixed in a twin-screw extruder, and the temperature of each section of the twin-screw extruder is set to T 1 =150℃, T 2 =160℃, T 3 =160℃, T 4 =165℃, T 5 =165℃, T 6 =170℃, the speed of twin-screw extruder is R=300r·min -1 ; After that, extrusion, cooling and granulation are used t...

Embodiment 2

[0037] First dissolve the polyvinyl alcohol in hot glycerol under stirring conditions, then disperse the crushed potassium chloride powder into the polyvinyl alcohol glycerol solution, and then spray the mixture into an inert hot air flow to make the solution The drop is shrunk into a spherical shape and then dried to obtain potassium chloride microcapsules.

[0038] 60 parts by mass of PBAT, 10 parts by mass of polylactic acid, 10 parts by mass of tapioca starch, 5 parts by mass of ethylene glycol, 10 parts by mass of potassium chloride microcapsules and 5 parts by mass of talc were mixed uniformly in a high-speed mixer, and then the mixture was mixed. Mixing in a twin-screw extruder, the temperature of each section of the twin-screw extruder is set to T 1 =155℃, T 2 =165℃, T 3 =165℃, T 4 =165℃, T 5 =170℃, T 6 =175℃, the speed of twin-screw extruder is R=300r·min -1 ; After that, extrusion, cooling and granulation are used to obtain the material for fully degradable top...

Embodiment 3

[0043] First dissolve the polyvinyl alcohol in hot glycerol under stirring conditions, then disperse the crushed calcium superphosphate into the polyvinyl alcohol glycerol solution, and then spray the mixture into an inert hot air flow to make droplets Shrink it into a spherical shape and then dry to obtain superphosphate microcapsules.

[0044] 30 parts by mass of poly PBAT, 30 parts by mass of polylactic acid, 10 parts by mass of corn starch, 5 parts by mass of propylene glycol, 20 parts by mass of superphosphate microcapsules and 5 parts by mass of light calcium carbonate were mixed uniformly in a high-speed mixer, and then The mixture is mixed in a twin-screw extruder, and the temperature of each section of the twin-screw extruder is set to T 1 =145°C, T 2 =155℃, T 3 =165℃, T 4 =165℃, T 5 =170℃, T 6 =175℃, the speed of twin-screw extruder is R=300r·min -1 ; After that, extrusion, cooling and granulation are used to obtain the material for the fully degradable top-dre...

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Abstract

The invention discloses a fully-degradable mulching film capable of applying fertilizer. The fully-degradable mulching film capable of applying the fertilizer is characterized by comprising the following components in percentage by mass: 30 to 60 percent of poly(butylene adipate-co-terephthalate) (PBAT), 10 to 30 percent of polylactic acid, 10 to 30 percent of starch, 5 to 10 percent of plasticizer, 0 to 2 percent of chain extender, 5 to 20 percent of chemical fertilizer microcapsule, 5 to 10 percent of filler and 0 to 5 percent of fully-degradable color master batch. The space region is covered by the fully-degradable mulching film to ensure that the temperature and the humidity meet the requirement, polyvinyl alcohol on the surfaces of the fertilizer microcapsules is dissolved to ensure that the surfaces of the fertilizer microcapsules have porous sustained-release structures, and the fertilizer is slowly separated out under the humid conditions for drop irrigation of crops, so that the function of applying the fertilizer to the crops is exerted. After the crops are harvested completely, the fully-degradable mulching film is not needed to be recovered.

Description

technical field [0001] The invention relates to a fully degradable top dressing mulch film and a preparation method thereof, belonging to the technical field of polymer materials. Background technique [0002] Plastic film is one of the important means of production in agricultural production. It can not only improve ground temperature, water retention, soil conservation, fertilizer conservation and fertilizer efficiency, but also weed control, pest control, drought and waterlogging resistance, salt suppression and seedling protection, and improvement of near-ground light. Thermal conditions, make the product hygienic and clean, and many other functions. [0003] As a large agricultural country, my country has a vast territory and great differences in climate. Therefore, the application and development of plastic film in the past three decades has been very rapid. It is the country with the largest consumption of plastic film, the largest coverage area, and the widest variet...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/00
Inventor 危伟张立斌金国轴盖付亮王淑敏
Owner WUHAN HUALI ENVIRONMENT PROTECTION SCI & TECH
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