Preparation method of lithium-rich anode strip of lithium ion battery
A lithium-ion battery and anode sheet technology, which is applied to battery electrodes, circuits, electrical components, etc., can solve problems such as ineffective control of lithium supplementation, poor cycle performance, and complicated processes, so as to achieve uniform lithium supplementation and increase energy density , The effect of simple process
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Embodiment 1
[0024] Example 1: This embodiment provides a method for preparing a lithium-rich anode sheet for a lithium-ion battery, which includes the following steps: Step 1, coating the anode slurry (including the anode active material, binder and conductive agent, etc., wherein the anode active material is graphite) Coating on the anode current collector, drying, so that the water content of the anode diaphragm does not exceed 300ppm, and the anode sheet to be supplemented with lithium is obtained.
[0025] Step 2: In the drying room, place the anode sheet to be supplemented with lithium prepared in the first step in the electrolyte (lithium salt concentration is 1mol / L), and after the anode diaphragm is fully infiltrated, put the anode diaphragm and The metal lithium strip is in double-channel contact. The contact temperature T is 10°C, the pressure P is 0, and the contact time is 10h, so that the lithium intercalation amount in the graphite is 5% of the total graphite capacity, and a...
Embodiment 2
[0026] Example 2:This embodiment provides a method for preparing a lithium-rich anode sheet for a lithium-ion battery, which includes the following steps: Step 1, coating the anode slurry (including the anode active material, binder and conductive agent, etc., wherein the anode active material is graphite) Coated on the anode current collector, dried so that the water content of the anode diaphragm does not exceed 300ppm, and cold pressed to obtain the anode sheet to be supplemented with lithium.
[0027] Step 2: In the drying room, place the anode sheet to be supplemented with lithium prepared in the first step in the electrolyte (lithium salt concentration is 0.1mol / L), and after the anode membrane is fully infiltrated, put the anode membrane The contact temperature T is 70°C, the pressure P is 0.2MPa, and the contact time is 2h, so that the lithium intercalation amount in the graphite is 15% of the total graphite capacity, and a lithium-rich anode sheet is obtained.
Embodiment 3
[0028] Example 3: This embodiment provides a method for preparing a lithium-rich anode sheet for a lithium-ion battery, including the following steps: Step 1, coating the anode slurry (including the anode active material, binder and conductive agent, etc., wherein the anode active material is silicon) Coated on the anode current collector, dried so that the water content of the anode diaphragm does not exceed 300ppm, and then cold pressed and slitting to obtain the anode sheet to be supplemented with lithium.
[0029] Step 2: In the drying room, place the anode sheet to be supplemented with lithium prepared in the first step in the electrolyte (lithium salt concentration is 2mol / L), and after the anode membrane is fully infiltrated, put the anode membrane and The metal lithium strip is in double-channel contact. The temperature T during contact is 150°C, the pressure P is 10MPa, and the contact time is 1min, so that the amount of lithium intercalated in silicon is 0.01% of th...
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