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Low-smoke, halogen-free and flame-retardant polyester elastomer thin-wall insulating material and preparation method thereof

A flame-retardant polyester and thin-wall insulation technology, which is applied in the field of wire and cable materials and its preparation, can solve the problems of poor processing safety, difficulty in flame retardancy reaching UL94V-O level, and low volume resistivity.

Active Publication Date: 2014-02-26
天津市普立泰高分子科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The above standards not only require cables to be safe, environmentally friendly, and energy-saving, but also specifically require high-temperature resistance to 125°C, wear resistance, oil resistance, halogen-free, cold resistance, high strength, and flame retardancy. (0.25mm), while traditional polyvinyl chloride (PVC), flame-retardant polyolefin materials, and fluorine-containing materials can no longer meet the requirements. Only low-smoke, halogen-free, flame-retardant polyester elastomer insulating materials can meet the above requirements.
[0004] At present, low-smoke, halogen-free, flame-retardant polyester elastomer thin-walled insulating materials have the following shortcomings: 1. The aging performance of high-temperature aging at 158°C and 168 hours is unqualified; 2. Poor processing safety and easy to degrade; 3. Poor insulation performance and low volume resistance 4. The flame retardant performance is difficult to reach the UL94V-O level

Method used

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  • Low-smoke, halogen-free and flame-retardant polyester elastomer thin-wall insulating material and preparation method thereof
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  • Low-smoke, halogen-free and flame-retardant polyester elastomer thin-wall insulating material and preparation method thereof

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Embodiment Construction

[0028] Taking low-smoke halogen-free flame-retardant polyester elastomer thin-wall insulating material and its preparation method as an example, combined with figure 1 The present invention is described in further detail, but not limited thereto. The raw materials used in the following examples are commercially available industrial products.

[0029] Embodiment is formulated according to the parts by weight shown in each component in table 3:

[0030] table 3

[0031] project

Implementation recipe

polyester elastomer

70

polyolefin

10

Nanocomposite flame retardant

20

Anti-hydrolysis stabilizer

2

Antioxidant A

0.5

Antioxidant B

0.3

lubricant

3

[0032] Preparation:

[0033] The preparation process steps of the present invention are as follows, according to the raw material metering 1, that is, according to the weight parts in the table, the raw material is added to the mixer and ...

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Abstract

The invention discloses a low-smoke, halogen-free and flame-retardant polyester elastomer thin-wall insulating material and a preparation method thereof. The insulating material mainly comprises the following components in parts by weight: 60-80 parts of polyester elastomer, 20-30 parts of nanocomposite flame retardant, 2-5 parts of anti-hydrolysis stabilizer, 1-2 parts of main antioxidant, 0.3-0.5 part of auxiliary antioxidant and 2-5 parts of lubricant. The method comprises the following steps of: uniformly mixing each component of the low-smoke, halogen-free and flame-retardant polyester elastomer thin-wall insulating material in a mixer at the temperature of 125 DEG C; and extruding and pelletizing in a double screw extruder. According to the insulating material, degradation and carbonization of acids are prevented, degradation and brittleness of the polyester elastomer in a high-heat and moist heat environment are eliminated by using the amine anti-hydrolysis stabilizer, long-term aging performance is ensured by using the special high-temperature-resistant antioxidant, the insulating performance is improved by blending polyolefin resin, and smooth and fine product appearance are ensured by using the special lubricant.

Description

1. Technical field [0001] The invention relates to a wire and cable material and a preparation method thereof, in particular to a low-smoke, halogen-free, flame-retardant polyester elastomer thin-wall insulating material used for rail transit locomotive vehicle cables and automobile wires and a preparation method thereof. 2. Background technology [0002] At present, with the rapid development of high-speed railway, urban rail transit and automobile industry, the introduction of EU ROHS and REACH environmental protection regulations and the need for safety, the requirements for cables for rail transit (high-speed trains, subways) and automotive wiring harnesses are getting higher and higher. It is required to meet the rolling stock cable standards such as GB / T12528, TB / T1484, BS EN50306, and the automotive wire standards such as QC / T730, ISO6722, Japan JASC3406 and JASO D611, American SAE1678, German DIN72551, and French NF R13414. [0003] The above standards not only requi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/00C08L23/20C08L75/00C08L83/04B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 董景茹汪全信董文博汪全伟
Owner 天津市普立泰高分子科技有限公司
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