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Method for preparing propylene through catalytic conversion of olefin raw material

A technology for catalytic conversion and raw materials, applied in catalytic cracking, hydrocarbon cracking to hydrocarbon production, and cracking, etc., can solve the problems of lower catalyst mass concentration, high oil contact temperature, lower reaction temperature, etc., and achieve shortened residence time and oil contact. The effect of low temperature and reduced dry gas yield

Active Publication Date: 2012-02-01
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented process involves performing chemical conversions between light hydrocarbons (olefms) from crude petroleum products or natural gases into more valuable materials like alcohols that have many applications for various industries including energy production and transportation. These processes involve reactors where liquid acidic solvents called liquids absorb specific types of molecules dissolved therein during processing steps. When these fluorocarboxylic acids break down they become volatile substances known as vapor bubbles. Vaporous components form an emulsion inside the vessel containing them while water droplets remain suspended within it. To separate this mixture effectively, some methods use special equipment designed specifically for handling small particles produced when breaking up heavy atoms.

Problems solved by technology

Technologies described include methods for efficiently making smaller amounts of certain types of chemical products called alkane compounds like butanes and diesel fuel without losing their effectiveness due to being converted during processing steps involving heat transferring between different components. Existing techniques involve modifying existing catalyst compositions based on specific needs rather than taking advantage of new ones.

Method used

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  • Method for preparing propylene through catalytic conversion of olefin raw material
  • Method for preparing propylene through catalytic conversion of olefin raw material

Examples

Experimental program
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Effect test

Embodiment 1

[0044] Take ZSP molecular sieve, kaolin, rentalite and pseudoboehmite according to the proportion, add decationized water and aluminum sol and beat for 120 minutes, and the pH value of the slurry is 3.0. The mixture was further beaten for 45 minutes, and then the resulting slurry was spray-dried at an inlet temperature of 500° C. and an exhaust gas temperature of 180° C. to obtain microspheres with an average particle diameter of 65 μm. The microspheres were calcined at 500°C for 1 hour to obtain 35wt% ZSP molecular sieve, 45wt% kaolin, 20wt% Al 2 o 3 The microsphere catalyst A.

[0045] Catalysts B-J were prepared according to the above method, and the compositions of the catalysts are shown in Table 1. The catalyst added with rectorite is finally calcined at 500-600° C. for 3-6 hours.

[0046] Table 1 Composition of Catalysts A-J

[0047] catalyst Molecular sieve type and content, wt% Kaolin, wt% Alumina, wt% ZSP molecular sieve silicon aluminum ratio ...

Embodiment 2~10

[0052] Examples 2-10 illustrate the effects of using the catalytic conversion method for raw materials rich in C4-C8 olefins provided by the present invention.

[0053] The catalyst was aged at 760°C with 100% steam for 10 hours, using a medium-scale test device, in which the inner diameter of the riser reactor was 18 mm and the height was 6 meters, and the inner diameter of the fluidized bed reactor was 64 mm and the height was 0.5 meters , the inner diameter of the dilute phase pipe at the outlet of the fluidized bed reactor is 30% of the inner diameter of the fluidized bed reactor. The loading capacity of catalyst in the compound reactor is 60 kilograms. The olefin raw material is sprayed into the fluidized bed reactor, which is mainly composed of 3.67wt% butane and 96.33wt% butene. The riser is used to convey the regenerated catalyst.

[0054] Reaction conditions and results are shown in Table 3-Table 5.

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Abstract

The invention relates to a method for preparing propylene through a catalytic conversion of an olefin raw material. The method comprises the steps of: introducing a raw material rich in C4<=> - C8<=> olefins into a fluidized bed reactor of a catalytic conversion device so as to contact and react with a catalytic cracking catalyst, separating a reaction product and a spent catalyst, subjecting the separated spent catalyst to steam stripping and coke burning regeneration for recycling use, and fractionating the separated product so as to obtain light olefins, gasoline, diesel oil, heavy oil and other low molecular saturated hydrocarbons. The catalytic conversion device consists of a riser reactor, a fluidized bed reactor, a settler, a stripper and a regenerator, wherein, the stripper is located under the fluidized bed reactor and is communicated with the bottom of the fluidized bed reactor, the outlet of the riser reactor is communicated with the bottom of the fluidized bed reactor, the outlet of which is communicated with the inlet of gas-solid separation equipment within the settler, and the catalyst outlet of the settler is communicated with the bottom of the fluidized bed reactor. The light olefins obtained by the method of the invention have high selectivity.

Description

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Claims

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Application Information

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Owner CHINA PETROLEUM & CHEM CORP
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