Method for recovering carbon from waste cathode carbon blocks of electrolytic aluminum
A technology for waste cathode carbon block and electrolytic aluminum, which is applied in the field of comprehensive utilization of solid waste resources, can solve problems such as secondary pollution of the environment, and achieve the effects of no secondary pollution, reduced production cost and low production cost.
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Embodiment 1
[0035] Such as figure 1 Shown, method of the present invention specifically comprises the following steps:
[0036] 1. Crushing and grinding, coarse crushing uses an impact crusher to crush the material to -200mm, enters the high-frequency vibration mill for fine crushing, and then enters the high-frequency vibration mill for grinding to -0.074mm, accounting for 70%.
[0037] 2. Water immersion: add water to the ground waste cathode carbon block to adjust the slurry, then carry out water immersion, the concentration of water immersion is 20%, stirring and leaching for 60 minutes, the leaching solution is evaporated to obtain sodium fluoride, and the distilled water is reused.
[0038] 3. Flotation, roughing I: filter the waste cathode carbon block powder after water immersion, wash and then filter, add water to the filter cake to make a slurry with a mass concentration of 20%, and add 400g / t waste cathode carbon block capture to the slurry. Collecting agent diesel oil, 160g / t...
Embodiment 2
[0041] Such as figure 1 Shown, method of the present invention specifically comprises the following steps:
[0042] 1. Crushing and grinding, coarse crushing uses a crusher to crush the material to -200mm, enters the high-frequency vibration mill for fine crushing, and then enters the high-frequency vibration mill for grinding to -0.074mm, accounting for 80%.
[0043] 2. Water immersion: Add water to the ground waste cathode carbon block to adjust the slurry, then carry out water immersion, the concentration of water immersion is 50%, stirring and leaching for 90 minutes, the leaching solution is evaporated to obtain sodium fluoride, and the distilled water is returned to the graphite recovery system.
[0044] 3. Flotation, roughing I: filter the waste cathode carbon block powder after water immersion, wash and then filter, add water to the filter cake to make a slurry with a mass concentration of 30%, and add 200g / t of spent cathode carbon block to the slurry. Collecting age...
Embodiment 3
[0047] Such as figure 1 Shown, method of the present invention specifically comprises the following steps:
[0048]1. Crushing and grinding, coarse crushing uses a crusher to crush the material to -200mm, enters the high-frequency vibration mill for fine crushing, and then enters the high-frequency vibration mill for grinding to -0.074mm, accounting for 60%.
[0049] 2. Water immersion: Add water to the ground waste cathode carbon block to adjust the slurry, then carry out water immersion, the concentration of water immersion is 10%, stirring and leaching for 30 minutes, the leaching solution is evaporated to obtain sodium fluoride, and the distilled water is returned to the graphite recovery system.
[0050] 3. Flotation, roughing I: filter the waste cathode carbon block powder after water immersion, wash and then filter, add water to the filter cake to make a pulp with a mass concentration of 10%, and add 800g / t waste cathode carbon block to the pulp. Collecting agent diese...
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