Volume hologram laminate manufacturing method
A technology of volume hologram and manufacturing method, which is applied in the photoengraving process of the pattern surface, the photosensitive material used for optical mechanical equipment, optics, etc., to achieve the effect of simple process
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[0307] The following examples will be given to describe the present invention concretely, but the present invention is not limited to the following examples.
[0308] 1-1. Embodiment 1
[0309] (1) Preparation of substrate for volume hologram formation
[0310] A polyethylene terephthalate (PET) film (Lumirror-50T60, manufactured by Toray Co., Ltd.) with a thickness of 50 μm was used as the base material, and a weight solution dissolved in a solvent was coated on the base material using a bar coater. The coating solution for forming a resin layer of polymethyl methacrylate having an average molecular weight of 15,000 was dried to form a resin layer so as to have a coating film thickness of 2 μm.
[0311] Next, a coating solution for forming a volume hologram layer having the following composition was directly applied on the resin layer using a dispenser to a dry film thickness of 10 μm to form a volume hologram layer.
[0312] (Coating solution for volume hologram layer form...
Embodiment 2
[0331] A volume hologram laminate was produced in the same manner as in Example 1 except that a polymethyl methacrylate having a weight average molecular weight of 35,000 was used.
Embodiment 3
[0333] A volume hologram laminate was produced by the same method as in Example 1 except that polymethyl methacrylate having a weight average molecular weight of 100,000 was used.
[0334] 1-4. Embodiment 4
[0335] A volume hologram laminate was produced in the same manner as in Example 1 except that a polyester resin with a weight average molecular weight of 40,000 (Vylon 270, manufactured by Toyobo Co., Ltd.) was used instead of polymethyl methacrylate.
[0336] 1-5. Comparative example 1
[0337] A volume hologram laminate was fabricated by the same method as in Example 1 except that the volume hologram layer was directly formed on the substrate without forming a resin layer.
[0338] 1-6. Evaluation of hologram recording characteristics
[0339] The transmittances of the volume hologram laminates obtained in Examples and Comparative Examples were measured with a spectrophotometer (UV-2450; manufactured by Shimadzu Corporation), and the diffraction efficiency, half-peak ...
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