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Catalyst module edge hardening liquid with activity

A catalyst module and hardening solution technology, which is applied in the direction of catalyst activation/preparation, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the problems of reduced service life of catalysts, non-protrusive catalyst wear, and end wear, etc., to achieve improved Effects of overall service life, improved module strength, and improved catalyst life

Active Publication Date: 2009-07-08
JIANGSU LONGYUAN CATALYST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The dust content of flue gas from foreign power plants is generally less than 30g / Nm 3 , the problem of wear on the catalyst is not prominent; while the types of coal used in China are relatively complex, especially in 2008 when the coal price soared, many power plants had to use low-quality coal, resulting in a very high dust content in the flue gas, many projects as high as 50-60g / Nm 3 , the existing technology does not do edge hardening, when the flue gas passes through the airflow channel of the catalyst, the fly ash particles hit the end of the catalyst rapidly, so the end wears the most serious, and as time goes by, the catalyst module will become shorter and shorter, The service life of the catalyst is greatly reduced, and it brings about the problem of how to fix the catalyst monomer in the module

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0010] Get the sodium metasilicate of 24g and 1g aluminum sulfate, the ammonium metavanadate of 16g ​​add in the water of 59g and stir to form hardening liquid, promptly in this hardening liquid, sodium metasilicate accounts for 24% by weight percentage content, ammonium metavanadate It accounts for 6% by weight in the hardening solution.

[0011] A 300MW coal-fired unit flue gas denitrification project, the dust content in the flue gas is 40g / Nm 3 , the concentration of nitrogen oxides is 400mg / Nm 3 , the flue gas temperature is 400°C, and the hardening process of the SCR honeycomb catalyst product is as follows:

[0012] Take two batches of honeycomb catalyst monomers that have been formed and dried in the same quantity. One batch of honeycomb catalyst monomers at both ends of the module are soaked in hardening solution at a distance of 15 mm from the end. Curing: After curing, the catalyst is sent to a kiln above 500°C for calcination, so that the hardening liquid can be ...

Embodiment 2

[0019] Get the sodium metasilicate of 40g, the aluminum sulfate of 3g, the ferrous sulfate of 1g and add in the water of 56g and stir to form hardening liquid, promptly in this hardening liquid, sodium metasilicate accounts for 40% by weight percentage content, ferrous sulfate is in The hardening solution accounts for 1% by weight.

[0020] A 300MW coal-fired unit flue gas denitrification project, the dust content in the flue gas is 60g / Nm 3 , the concentration of nitrogen oxides is 400mg / Nm 3 , the flue gas temperature is 370°C, and the hardening process of the SCR honeycomb catalyst product is as follows:

[0021] Take two batches of honeycomb catalyst monomers that have been formed and dried in the same quantity. One batch of honeycomb catalyst monomers at both ends of the module are soaked in hardening solution at a distance of 35 mm from the end. Curing: After curing, the catalyst is sent to a kiln above 500°C for calcination, so that the hardening liquid can be convert...

Embodiment 3

[0026] Get 32g of sodium metasilicate, 2g of aluminum sulfate, and 5g of manganese nitrate and add them into 61g of water and stir to form a hardening solution, that is, sodium metasilicate accounts for 32% by weight in the hardening solution, and manganese nitrate 5% by weight in the liquid.

[0027] A 600MW coal-fired unit flue gas denitrification project, the dust content in the flue gas is 50g / Nm 3 , the concentration of nitrogen oxides is 400mg / Nm 3 , the flue gas temperature is 300°C, and the hardening process of the SCR honeycomb catalyst product is as follows:

[0028] Take two batches of honeycomb catalyst monomers that have been formed and dried in the same quantity. One batch of honeycomb catalyst monomers at both ends of the module are soaked in hardening solution at a distance of 25mm from the end. Curing: After curing, the catalyst is sent to a kiln above 500°C for calcination, so that the hardening liquid can be converted into effective hardening and active co...

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PUM

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Abstract

The invention discloses an active catalyst module edge hardening liquid, comprising the following ingredients: 30 to 50 weight percent of sodium silicate and active compositions, wherein the active compositions are one of or the mixture of two or more than two of ammonium metavanadate, green copperas and manganese nitrate, the ammonium metavanadate accounts for 0 to 1 weight percent in the hardening liquid, the manganese nitrate accounts for 0 to 5 weight percent in the hardening liquid, and the balance is water. The hardening liquid of the invention causes the end of a catalyst module to be much more antiabrasive, thereby greatly increasing the integral service life and the strength of the module; and under the same condition, the abrasion weight loss ratio of the catalyst module can be reduced by 20 percent, and the service life of the catalyst can be prolonged by more than 30 percent.

Description

technical field [0001] The invention discloses an active catalyst module edge hardening solution. Background technique [0002] At present, the pollution of nitrogen oxides continues to intensify, especially in some big cities such as Beijing, Shanghai, Guangzhou, etc., the nitrogen oxide content greatly exceeds the standard, and even photochemical smog pollution appears in some areas, which has a serious impact on economic development and people's lives . Thermal power plants are the largest pollution source of NOx emissions, accounting for more than 36% of total emissions. Controlling nitrogen oxide emissions has become the third key pollution control task for thermal power plants after flue gas dust removal and desulfurization. With the promulgation of "Emission Standards of Air Pollutants for Thermal Power Plants" (GB13223-2003), the simple low-nitrogen combustion technology can no longer meet the requirements of the current emission standards. Domestic thermal power p...

Claims

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Application Information

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IPC IPC(8): B01J35/04B01J27/24B01J27/053B01J27/25B01J37/02B01D53/56
Inventor 曹莉莉陈建军祁德祥
Owner JIANGSU LONGYUAN CATALYST CO LTD
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