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Reboiler cleaning agent and cleaning method thereof

A technology of reboiler and cleaning agent, applied in the field of cleaning agent, can solve the problems of reboiler cleaning problem, difficult cleaning and descaling work, and high cleaning frequency, so that the descaling process is simple but not complicated, and it is economical. and environmental effects

Active Publication Date: 2008-09-03
HUAWEI TEHCHNOLOGIES CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Taking methylnaphthalene as an example, there are α-methylnaphthalene and β-methylnaphthalene. Although the molecular weight of the isomers is the same and the difference in boiling point is less than 2°C, their chemical properties are very different, which leads to complex chemical reactions.
It is precisely because of the above reasons that after long-term use of the reboiler with heat transfer oil as the heating medium, fouling will occur on the wall of the reboiler shell side tube, and the organic scaling produced by the thermal decomposition or polycondensation of the heat transfer oil for a long time It has strong stubbornness, and due to the structural characteristics of the reboiler itself, once the dirt is generated, it is very difficult to clean and remove the scale. It is almost impossible to use solvents, compound solvents, and descaling agents in the prior art.
[0009] For the cleaning of the reboiler, chemical cleaning or high-pressure water cleaning are mostly used at present. Due to the gap between the calculated equipment volume and the actual volume of the former, it is easy to cause the dosage of cleaning agents to fail to meet the actual demand and not reach the expected value. Cleaning effect; the latter uses high-pressure water cleaning. Due to the high cleaning water pressure, the tubes are easily damaged (breakdown), and the cleaning effect is not ideal, resulting in high cleaning frequency, which seriously affects the safety and stability of the device and the smooth long-term production. conduct
Up to now, the industry has always been plagued by the problem of cleaning the reboiler, and is also actively exploring and trying, but so far there is no ideal cleaning agent

Method used

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  • Reboiler cleaning agent and cleaning method thereof
  • Reboiler cleaning agent and cleaning method thereof
  • Reboiler cleaning agent and cleaning method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] First, drain all the heat transfer oil in the reboiler 9, then close the heat transfer oil entering the reboiler pipeline valve 7 and the reboiler heat transfer oil outlet pipeline valve 2, and simultaneously open the cleaning agent to enter the reboiler pipeline valve 6 and clean The agent enters the cleaning agent storage tank inlet pipeline valve 3; fills in the cleaning agent storage tank 4 by the following raw materials in parts by weight: 5 parts of α-methylnaphthalene, 52 parts of β-methylnaphthalene, 15 parts of naphthalene and from The reboiler cleaning agent purchased in the market from 28 parts of heavy aromatic solvents with a distillation range of 190-270°C provided by Wujiang Hongwei Environmental Protection Auxiliary Co., Ltd., Wujiang City, Jiangsu Province, China, and then start conveying and reboil Pipeline pump 5 for cleaner cleaning agent, the control flow rate is 30m 3 / h, the reboiler cleaning agent is introduced into the reboiler 9 through the reb...

Embodiment 2

[0027] Only change the selected α-methylnaphthalene to 8 parts, β-methylnaphthalene to 58 parts, naphthalene to 2 parts, heavy aromatic hydrocarbon solvent to 32 parts, and change to Pingling, Liyang City, Jiangsu Province, China Liyang Chengxing Chemical Co., Ltd., No. 38 East Road, provided heavy aromatic solvents with a distillation range of 200-245°C, and the circulation flow rate of the cleaning agent was changed to 35m 3 / h, the temperature of the cleaning agent cycle cleaning is changed to 100°C, and the cycle cleaning time is changed to 8.5h. All the other are with embodiment 1.

Embodiment 3

[0029] Only change the selected α-methylnaphthalene to 10 parts, β-methylnaphthalene to 65 parts, naphthalene to 6 parts, heavy aromatic solvent to 19 parts, and the cleaning agent circulation flow to 25m 3 / h, the temperature of cleaning agent circulation cleaning is changed into 85 ℃, and the time of circulation cleaning is changed into 15h, after cleaning, the reboiler cleaning agent containing organic dirt discharged from reboiler 9 is used as fuel, and all the other same Example 1.

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Abstract

A detergent for reboiler and cleaning method thereof are disclosed, which pertains to the detergent field. The detergent comprises raw materials with weight proportion as follows: alpha-methylnaphthanlene 5-10 parts; beta-methylnaphthanlene 50-70 parts; naphthalin 2-15 parts; heavy aromatic hydrocarbon solvent 10-35 parts. Advantages are that organic scale formation formed in the reboiler because of decomposition of heat conductive oil due to long-term heating or condensation is effectively removed; contaminant release process is simple; detergent after contaminant release can be recycled and reused, which is economic and environmental protective.

Description

technical field [0001] The invention belongs to the technical field of cleaning agents, and in particular relates to a cleaning agent for a reboiler. Background technique [0002] With the rapid development of science and technology, in the process of synthesizing, preparing and refining corresponding products in petroleum, chemical, pharmaceutical and dye industries, more and more complex equipment are required, for example, large heat exchangers , condenser, reboiler, etc. In the tube side and shell side of these devices, especially the dirt and organic fouling in the shell side, manual cleaning is very difficult. If these scales are not removed, the heat transfer efficiency will be affected and the energy consumption will be increased. In severe cases, normal production will be affected. This requires a special cleaning agent for cleaning. [0003] In the prior art, solvents and compound solvents are used to clean condensers and heat exchangers; chemical reagents and s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C11D7/50F28G9/00C11D7/24
Inventor 苏仁球陈绮峰李凤娟刘忠云陈丽萍
Owner HUAWEI TEHCHNOLOGIES CO LTD
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