Removable pressure-sensitive adhesive composition and pressure-sensitive adhesive tape or sheet
A pressure-sensitive adhesive and pressure-sensitive adhesive layer technology, applied in the field of pressure-sensitive adhesive compositions, pressure-sensitive adhesive tapes or sheets, can solve the problem of reducing the reactivity of UV-curable compounds, difficult to completely Prevent low molecular weight components from migrating, migrating, etc.
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preparation Embodiment 1
[0105] Copolymerize 75 parts by weight of methyl acrylate, 10 parts by weight of methoxyethyl acrylate, 10 parts by weight of N-vinylpyrrolidone and 5 parts by weight of 2-hydroxyethyl acrylate in ethyl acetate , to obtain a solution containing an acrylic acid copolymer (sometimes referred to as an acrylic acid copolymer solution (A)).
[0106] Then, 60 parts by weight of 2-methacryloyloxyethyl isocyanate was added to the above-mentioned solution (A) containing acrylic acid copolymer, and then 0.1 part by weight of dibutyltin dilaurate was added as a catalyst, and then it was heated at 50° C. The reaction was carried out for 24 hours to obtain a solution containing a double bond-introducing type acrylic polymer (weight average molecular weight: 500,000) having a carbon-carbon double bond at the end of the side chain (solution (A) containing a double bond-introducing type acrylic polymer). The double bond-introducing type acrylic polymer has the form of isocyanate groups of 2-m...
preparation Embodiment 2
[0109] Copolymerize 75 parts by weight of methyl acrylate, 10 parts by weight of methoxyethyl acrylate, 10 parts by weight of N-vinylpyrrolidone and 10 parts by weight of 2-hydroxyethyl acrylate in ethyl acetate , to obtain a solution containing an acrylic acid copolymer (sometimes referred to as an acrylic acid copolymer solution (B)).
[0110] Then, 12 parts by weight of 2-methacryloyloxyethyl isocyanate was added to the above-mentioned solution (B) containing acrylic acid copolymer, and then 0.1 part by weight of dibutyltin dilaurate was added as a catalyst, and then it was heated at 50° C. The reaction was carried out for 24 hours to obtain a solution containing a double bond-introducing type acrylic polymer (weight-average molecular weight: 600,000) having a carbon-carbon double bond at the end of the side chain (solution (B) containing a double bond-introducing type acrylic polymer). The double bond-introducing type acrylic polymer has the form of isocyanate groups of 2-...
preparation Embodiment 3
[0113] A UV-curable acrylic pressure-sensitive adhesive solution (sometimes referred to as pressure-sensitive adhesive solution (C)) was prepared in the same manner as in Preparation Example 1 of the UV-curable acrylic adhesive solution, except that The photopolymerization initiator (trade name "Irgacure 2959", manufactured by Ciba Specialty Chemicals Co.) was replaced with a photopolymerization initiator (trade name "Irgacure 651", manufactured by Ciba Specialty Chemicals Co.).
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