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Device for calcining aluminum oxide clinker by directly utilizing coal powder and method thereof

A technology for calcining alumina and clinker, applied in alumina/hydroxide preparation and other directions, can solve the problems of land and water pollution, lack of good, environmental pollution, etc., achieve low energy consumption and efficient collection, improve reaction speed, reduce The effect of energy consumption

Inactive Publication Date: 2008-03-26
XI AN JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The operation of this kind of pulverized coal boiler brings two more serious problems. One is that a large amount of fly ash by-product will cause serious pollution problems to land and water sources.
Second, the sulfur dioxide and a small amount of fly ash in the flue gas also bring environmental pollution to the atmosphere
[0013] In 2001, Rayalu et al studied the synthesis of zeolite from flyash after burning bituminous coal and lignite (S.S.Rayalu, J.S.Udhoji, K.N.Munshi, M.Z.Hasan. Highlycrystalline zeolite-a from flyash of bituminous and lignite coalcombustion[J].Journal of Hazardous Materials, 2001, 88(1): 107-121), the test shows that SiO 2 / Al 2 o 3 When the ratio is 3.47, it is most beneficial to the synthesis of porous zeolite, which shows that it is feasible to synthesize different materials using fly ash; this document describes the utilization of fly ash in India (R.H.Matjie, J.R.Bunt, J.H.P. .Extraction of alumina from coal fly ash generated from a selected low rank bituminous South African coal[J].Minerals engineering.2004, 18:299~310), India is similar to China, 75% of electricity comes from thermal power generation, India currently pulverized coal The ash utilization rate also reaches 27% (the world's average level reaches 33%), which is much higher than that in China. The article also mentions the extraction of alumina in fly ash, but there is no good way
[0014] R.H.Matjie et al. (P.Asokan, Mohini Saxena, Shyam R.Asolekar.Coalcombustion residues-environmental implications and recycling potentials[J].Resources Conservation and Recycling.2005,43:239~262) on high aluminum coal (coal ash contains 30 % Aluminum, 1.5% Titanium, 2.5% Aluminum Oxide, 9.5% Calcium Oxide, 60% Silica) for extraction research, mixing fly ash with Calcium Oxide and calcining at 1000℃~1200℃ to generate acid or alkali energy Dissolved calcium aluminate, and then washed with sulfuric acid to produce a solution containing iron, aluminum and titanium, at 80°C, the concentration is 6.12mol / m 3 Immersed in acid for 4 hours, the final aluminum recovery efficiency reached 85%, and the extracted aluminum-containing substances contained 99.4% of high-purity alumina. It has application value, but the method in this article is still re-calcination method, and the energy consumption is very high

Method used

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  • Device for calcining aluminum oxide clinker by directly utilizing coal powder and method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] 1. Select the high-alumina raw coal from the Zhungeer area of ​​Inner Mongolia. The alumina content in the fly ash after normal combustion is 50%, and the ash content is 10%. The local limestone in Xi'an is selected, and the purity of calcium oxide is >90%. Ratio of high alumina coal to limestone: 8:2.

[0048] 2. Use ordinary ball milling method to crush, the ball milling speed is 150 rpm, and the ball milling is continued for 1 hour to prepare powder with an average particle size of less than 100 microns.

[0049] 3. The uniform powder feeding rate of the screw feeder is 300g / min, and the compressed air volume is 0.3m 3 / minute.

[0050] 4. The design height of the furnace is 3 meters, so that the residence time of the coal ash powder in the furnace is 1 second, and the temperature of the furnace is controlled at 1250 ° C to 1300 ° C.

[0051] 5. The fly ash collection device is a cyclone separation and cloth bag separation and an integrated collection device. This...

Embodiment 2

[0053] The difference between this example and Example 1 is that the ratio of high-alumina coal to limestone is 7:3, the mass ratio of calcium aluminate in the obtained alumina clinker reaches 20% to 24%, and the actual conversion rate of alumina clinker reaches 90%. %above.

Embodiment 3

[0055] The difference between this example and Example 1 is that the ratio of high-alumina coal to limestone is 5:5, the mass ratio of calcium aluminate in the obtained alumina clinker reaches 16% to 20%, and the actual conversion rate of alumina clinker reaches 90%. %above.

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Abstract

The apparatus for calcining alumina clinker with coal powder includes one hearth with one temperature measuring thermocouple connected to the first temperature controlling instrument to measure the temperature in the upper part of the hearth and one temperature controlling thermocouple connected to the second temperature controlling instrument to control the temperature rise in the hearth, one coal feeder in the inlet of the hearth, one coal powder mixer with burner connected to the coal feeder, one cyclonic separator and one induced draft fan connected to the outlet of the hearth, one flowmeter and one air flow rate regulating valve connected between the coal powder mixer and one air tank, and one air compressor connected to the air tank. During calcining alumina clinker proper amount of calcium containing material is added into high aluminum coal powder, and the present invention has low power consumption for extracting alumina from coal powder.

Description

technical field [0001] The invention belongs to the technical scope of high-efficiency pulverized coal combustion and high-efficiency and low-energy utilization of low-grade resources, and particularly relates to a device and method for preparing pulverized coal, high-efficiency pulverized coal combustion, pneumatic transportation, high-temperature separation of fly ash, and calcining alumina clinker. In particular, a device and method for directly using coal powder to calcinate alumina clinker. Background technique [0002] With the super-rapid development of thermal power plants, the amount of coal burned by power plant boilers reaches 1.2-1.4 billion tons every year, and the amount of fly ash discharged every year reaches 200-400 million tons, especially in major cities such as Ningxia, Inner Mongolia, Shanxi, and Shaanxi. Coal-producing areas produce a large amount of high-alumina coal every year, of which the amount of fly ash with an alumina content higher than 30% is ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F7/30
Inventor 谭厚章赵鹏徐通模
Owner XI AN JIAOTONG UNIV
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