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Silicone release coating compositions

a technology of coating compositions and silicon ions, applied in the direction of coatings, organic chemistry, group 5/15 element organic compounds, etc., can solve the problem of adding significant cost to the formulated release coating bath, and achieve the effect of reducing the pt catalyst level and fast cur

Inactive Publication Date: 2009-09-22
DOW CORNING CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0045]The release coating compositions of the present invention have the advantages of rapid cure for fast line speeds, typically 0.8-3.0 seconds at a web temperature of 100-115° C., and reduced smoking and extractables when used with release modifiers, described in EP-A-1070734, together with the economic advantage of being able to use low platinum metal catalyst levels.

Problems solved by technology

This adds significant cost to the formulated release coating bath.

Method used

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  • Silicone release coating compositions
  • Silicone release coating compositions
  • Silicone release coating compositions

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0047]350 g tetra(dimethylvinylsiloxy)silane and 4.65 kg D4 were mixed at 20° C. and 0.20 g polyaminophosphazenium hydroxide catalyst was admixed (40 ppm based on siloxanes), causing a rapid increase in viscosity. After a period of 30 seconds the reaction mixture was then neutralised with 25 g (0.5%) polyacrylic acid of molecular weight Mw=2000. Low molecular weight components were stripped out of the mixture and the reaction product was filtered to remove excess polyacrylic acid and neutralised catalyst. The product was a dimethylvinyl-termiinated Q-branched polysiloxane having a DP of 160 and viscosity of 220 mPa·s.

[0048]100 g of this Q-branched polysiloxane was mixed with 3.3 g trimethyl-terminated poly(methylhydrogensiloxane) having a viscosity of 11 mPa·s and 0.8 g parts of the catalyst reaction product of chloroplatinic acid and divinyltetramethyldisiloxane (0.5% Pt; 40 ppm Pt based on siloxane) to form a release coating composition. This composition was coated on glassine pap...

examples 2 to 9

[0051]Example 1 was repeated varying the temperature of preparation of the dimethylvinyl-terminated Q-branched polysiloxane and the molecular weight and amount of the polyacrylic acid used for neutralisation. The extractables of various cured release coatings were measured as described in Example 1 and are shown in Table 1 below

[0052]

TABLE 1Example123456789Mw of Acid2000200020002000450000750000750000750000750000Quantity / %0.520.521.250.520.52Temperature / C.202070704520207070Extractables100 C. / 15 sces9.19.510.77.97.18.96.38.75.7115 C. / 15 sces7.38.38.88.66.49.478.35.5

examples 10 to 12

[0053]The process of Example 6 was repeated using lower levels of the phosphazene base catalyst in preparation of the dimethylvinyl-terminated Q-branched polysiloxane. Release coatings were prepared from the resulting polymers and cured and tested as described in Example 1. The results are shown in Table 2.

[0054]

TABLE 2Example101112Quantity of PhosphazineExtractables12.25 ppm10 ppm5 ppm100 C. / 15 secs12.212.39.9115 C. / 15 secs6.96.88.7

[0055]It will be seen that in all cases the release coating of the invention is more fully cured (less extractables) than the coating of the Comparative Example C1.

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Abstract

A release coating composition according to the present invention comprises an alkenyl functional polysiloxane (1), a silicon hydride functional polysiloxane (11) and a catalyst (111) comprising a platinum group metal. The alkenyl functional polysiloxane (1) is an alkenylterminated polysiloxane prepared by siloxane polycondensation and / or equilibration using a phosphazene base catalyst followed by neutralisation with an acidic neutralising agent. The level of catalyst (III) in the composition can be as low as 2-40 parts per million platinum group metal by weight.

Description

CROSS REFERENCE TO RELATED APPLICATIONS[0001]This application is a U.S. national stage filing under 35 U.S.C. §371 of PCT Application No. PCT / EP2004 / 00780 filed on Jul. 2, 2004, currently pending, which claims the benefit of GB Patent Application No. 0316162.7 filed Jul. 10, 2003 under 35 U.S.C. §119 (a)-(d) and 35 U.S.C. §365(a). PCT Application No. PCT / EP2004 / 00780 and Patent Application No. 0316162.7 are hereby incorporated by reference.FIELD OF THE INVENTION[0002]This invention relates to silicone based release coating compositions and to novel branched alkenyl functional siloxanes, useful in release compositions, and their preparation.BACKGROUND TO THE INVENTION[0003]Silicone based release coatings are useful in applications where relatively non-adhesive surfaces are required. Single sided liners, for example, backing papers for pressure sensitive adhesive labels, are usually adapted to temporarily retain the labels without affecting the adhesive properties of the labels. Doubl...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): C08G77/04C07F9/06C08G77/08C08G77/12C08G77/20C08L83/04C09D183/04
CPCC09D183/04C08L83/04C08G77/20C08G77/12C08G77/14C08G77/80C08G77/16C08G77/18C08G77/24C08G77/26C08G77/70C08L83/00
Inventor CRAY, STEPHEN EDWARDEKELAND, ROBERT ALANHUPFIELD, PETER CHESHIREO'HARE, SARAHRICH, DAVID A.THIBAUT, MARC
Owner DOW CORNING CORP
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