Plastic material
a technology of plastic materials and polyols, applied in the field of plastic materials, can solve the problems of disadvantages of petrochemicals such as polyester or polyether polyols, add to the cost of polyols and the disadvantageous environmental effects of its production, and the price of polyols is prone to be somewhat unpredictabl
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example 1
50 gSoy Oil 5 gEthylene Glycol (cross-linker) 1 gFront end catalyst (DABCO 33-LV ®;33% triethylenediamine and67% dipropylene glycol) 1 gBlow catalyst (DABCO ® BL-22; a tertiary amine catalyst) 4 gMethyl Isobutyl Ketone (blowing agent)
[0043]Blown soy oil has a molecular weight of about 278, while the ethylene glycol has a molecular weight of about 62. Thus, the molar ratio of ethylene glycol to blown soy oil is 0.22:1. Since the ethylene glycol has two hydroxyl (OH) groups with which to cross-link the constituent fatty acids of the blown soy oil, the molar ratio of the hydroxyl (OH) groups of the ethylene glycol to soy oil is about 0.45:1. The resulting B-side was then combined with an A-side material in a ratio of 50 parts A-side to 100 parts B-side. The A-side material is comprised of Mondur® 448, a modified monomeric diphenylmethane diisocyanate (pMDI).
[0044]The cure was acceptable; however, the cellular material remained tacky at the surface for 20 minutes.
example 2
[0045]The B-side is the same as that of Example 1. The A-side is comprised of MA-2901, a modified diphenylmethane diisocyanate. The B-side was combined with the A-side in a ratio of 52 parts A-side to 100 parts B-side. The cure was acceptable, although the cellular material remained tacky for 12 minutes.
example 3
[0046]The A-side was the same as Example 2. The B-side was again the same as that of Example 1, except that 1.5 parts of methanol were added as additional blowing agent. The ratio was 52 parts A-side to 100 parts B-side. The sample cured in 1 hour. It was not a favorable result in that the cellular material foamed and then fell back to solid and rose again.
[0047]The methanol apparently had an adverse affect.
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