Inkjet printer having printhead and ink for minimizing corrosion of exposed corrodible structures within printhead

Abstract

An inkjet printer includes: an inkjet printhead having an exposed corrodible structure containing silicon nitride, borophosphosilicate glass (BPSG) or silicon oxide; and an ink reservoir containing said ink which is in fluid communication with said printhead. The ink includes: water; a dye; and a metal additive for minimizing corrosion of the exposed structure.

Description

FIELD OF THE INVENTION[0001]This invention relates to inkjet inks for inkjet printers. It has been developed primarily for minimizing corrosion of corrodible structures in printheads by dye-based inkjet inks.CROSS REFERENCES[0002]The following patents or patent applications filed by the applicant or assignee of the present invention are hereby incorporated by cross-reference.6,755,5097,222,9437,188,4197,168,1667,086,71912 / 246,33212 / 246,3367,246,8867,128,4007,108,3556,991,3227,287,8367,118,19710 / 728,7847,364,2697,077,4936,962,40210 / 728,8037,147,30810 / 728,7797,118,1987,168,7907,172,2707,229,1556,830,3187,195,3427,175,2617,465,0357,108,3567,118,20210 / 773,1867,134,7447,134,7437,182,4397,210,7687,465,0367,134,7457,156,4847,118,2017,111,9267,431,4337,401,9017,468,13911 / 744,88511 / 097,3087,328,9787,334,8767,147,3067,448,7347,425,05011 / 014,76411 / 014,7637,331,6637,360,8617,328,9737,427,1217,407,2627,303,2527,249,82211 / 014,7627,311,3827,360,8607,364,2577,390,0757,350,8967,429,0967,384,1357,331...

AI Technical Summary

Benefits of technology

[0015]an ink reservoir containing the ink, the ink reservoir being in fluid communication with the printhead,wherein the ink comprises: water; a dye; and a metal additive for minimizing corrosion of the exposed surface, the metal additive comprising one or more metals selected from the group consisting of: Al(III), Fe(III), Fe(II), Cu(II), Cu(I), Bi(III), Cr(III), Mg(II), Sr(II), Ba(II), Ce(III), Ag(I), Al, Fe, Ce, Cu, Cr, Mg and Ag.

[0094]In an eighth aspect, there is provided a use of an inkjet ink as described in connection with the seventh aspect for inhibiting corrosion of a corrodible structure in a printhead, the corrodible structure being comprised of silicon nitride, borophosphosilicate glass (BPSG) or silicon oxide.

Problems solved by technology

In the Applicant's bi-layered nozzle plate structures, comprising a lower layer of silicon nitride and an upper layer of silicon oxide, an unacceptable degree of roof delamination has been observed.

This delamination results in a significant reduction in print quality, especially in black ink channels where delamination is most severe.

However, some corrosion of silicon oxide was also observed, albeit at a relatively slower rate of corrosion than silicon nitride.

Clearly, if ink comes into contact with any CMOS Metal layers then this is potentially catastrophic for printhead operation.

Although many inks do not affect this BPSG layer (or other silicon oxide layers) in the printhead IC, it has been found that some inks cause significant corrosion of the BPSG layer which is problematic for printhead longevity.

However, this type of mechanical solution to the problem of corrosion has the significant drawback that it requires a more complex printhead design, as well as the development and optimization of suitable MEMS fabrication processes.

On a practical level, redesigning printheads is highly undesirable, especially when optimized printhead fabrication processes are well-established and suitable for mass-production.

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