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Ternary composite octahedrite type titanium dioxide photocatalyst and preparation process thereof

A titanium dioxide and anatase-type technology, which is applied in the field of ternary composite anatase-type TiO2 photocatalyst and its preparation, can solve the problems of reduced photocatalytic performance of composite photocatalysts, large manpower and material resources, etc., and the method is simple and feasible, Low cost and wide application effect

Inactive Publication Date: 2007-03-14
NANTONG SUZHONG TEXTILE +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the activated carbon used as a carrier is micron-sized, although the recovery process reduces TiO 2 The loss and waste of the catalyst still need to be filtered and separated, which still requires a lot of manpower and material resources
[0004] In order to simplify the separation process of catalysts, some researchers used nano-TiO 2 A magnetic composite photocatalyst with a core-shell structure is loaded on magnetic particles, and the composite catalyst can be easily separated from the treated wastewater system by means of an external magnetic field, but there is a problem that the photocatalytic performance of the composite photocatalyst is reduced. up

Method used

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  • Ternary composite octahedrite type titanium dioxide photocatalyst and preparation process thereof
  • Ternary composite octahedrite type titanium dioxide photocatalyst and preparation process thereof
  • Ternary composite octahedrite type titanium dioxide photocatalyst and preparation process thereof

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Embodiment 1

[0023] A ternary composite anatase type titanium dioxide photocatalyst. Magnetic nanoparticles are adsorbed on activated carbon to form magnetic activated carbon. Titanium dioxide is loaded on the magnetic activated carbon. The mass ratio of magnetic nanoparticles / activated carbon is 1:1~1: 9. Magnetic activated carbon / TiO 2 The mass ratio is 1:1~1:5. In this embodiment, the mass ratio of magnetic nanoparticles to activated carbon can be 1:1, 1:9, 1:3, 1:5 or 1:8. Magnetic activated carbon With TiO 2 The mass ratio can be 1:1, 1:5, 1:3 or 1:4. Fe may be used for the above magnetic nanoparticles 3 O 4 , Γ-Fe 2 O 3 Or nickel ferrite.

Embodiment 2

[0025] A preparation method for manufacturing the above-mentioned ternary composite anatase titanium dioxide photocatalyst:

[0026] The first step: Take the magnetic nano-particle sol and activated carbon, add the activated carbon to the magnetic nano-particle sol sol according to the mass ratio of the magnetic nano-particles to the activated carbon at a ratio of 1:1 to 1:9, stir and make the magnetic nanoparticles be coated with the activated carbon It is adsorbed and separated by a magnetic field, and dried at 40-80°C to prepare magnetic activated carbon with magnetism, which can be used as a carrier of titanium dioxide. In this embodiment, the mass ratio of magnetic nanoparticles to activated carbon can be 1: 1. 1:9, 1:4, 1:6 or 1:7, the drying temperature is 40℃, 80℃, 45℃, 62℃, 72℃ or 53℃;

[0027] Step 2: Take the anatase titanium dioxide sol, immerse the magnetic activated carbon in the anatase titanium dioxide sol so that the mass ratio of the magnetic activated carbon to ...

Embodiment 3

[0030] One for preparing TiO 2 / Fe 3 O 4 / Activated carbon ternary composite photocatalyst is prepared by first pressing Fe 3 O 4 The ratio of active carbon to active carbon is 1:5 to prepare magnetic active carbon, and then 180 ml of titanium dioxide prepared by the sol-gel method is loaded on 3 grams of magnetic active carbon.

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Abstract

The invention relates to a method for preparing ternary compound anatase titania photocatalyst. Wherein, it uses magnetic nanometer particle sol and active carbon whose mass ratio is 1:1-1:9; then puts the active carbon into magnetic nanometer particle sol, to be mixed; therefore, the magnetic nanometer particles are adsorbed by the active carbon; then separating them via magnetic field to be dried at 40-80Deg. C, to obtain magnetic active carbon whose carrier is titania; then emerging the magnetic active carbon in anatase titania sol, to make the mass ratio between the magnetic active carbon and anatase titania 1:1-1:5; mixing for 0.5 hour and evaporating the suspension into powder; said powder is the final compound photocatalyst. The invention can prepare porous active carbon with high adsorption ability.

Description

Technical field [0001] The invention relates to a photocatalyst and a preparation method thereof, in particular to a ternary composite anatase TiO 2 Photocatalyst and its preparation method. Background technique [0002] Since Fujishima and Honda reported anatase TiO in Nature magazine in 1972 2 Since photoelectrodes can produce hydrogen by hydrolysis, the rapid charge separation and redox reactions induced by semiconductor materials based on the wide band gap under light have attracted widespread attention in the research and application of photocatalytic oxidation of organic wastewater. Among them, nano TiO 2 It has the advantages of resistance to chemical and light corrosion, stable properties, non-toxic, high catalytic activity, fast reaction speed, non-selective degradation of organic matter, easy to make it completely mineralized, and no secondary pollution. It is generally regarded as the most promising application catalyst of light. TiO 2 There are three crystal types of ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J21/06B01J21/18B82B1/00C02F1/58H01F1/11
Inventor 敖燕辉付德刚沈迅伟徐晶晶林义华袁春伟
Owner NANTONG SUZHONG TEXTILE
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