Repairing agent for repairing radioactive contaminated soil and repairing use method of repairing agent
A soil remediation and remediation agent technology, applied in the field of soil remediation, can solve problems such as damage, secondary pollution, and insufficient removal of radionuclides, and achieve excellent decontamination efficiency, high practical value, and suitable for large-scale applications.
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preparation example 1
[0036] 1kg of chitosan was dissolved in 15kg of 1wt% acetic acid, stirred at room temperature for 6h; then 0.25kg of succinic anhydride dissolved in 1kg of acetone was added, and the reaction was stirred at room temperature for 10h; then, 1N was added to the mixture at room temperature The pH value was adjusted to 7-8 with NaOH, and stirred for 8 h; the reaction mixture was dialyzed with deionized water for 2 days using a dialysis bag with a molecular weight cut-off of 3500 Da, the dialysate was distilled under reduced pressure to remove the solvent, and then freeze-dried to obtain succinic acid-modified chitosan Sugar 0.8Kg.
Embodiment 1-3
[0038] Add 60 g of diethylene triamine penta(methylene phosphonic acid), 120 g of succinic acid-modified chitosan of Preparation Example 1, 60 g of sodium metaaluminate, and 160 g of concentrated hydrochloric acid (37%) into 600 g of deionized water , heated to 35° C. under stirring to dissolve completely, and after cooling, diluted to 1 / 8, 1 / 5, and 1 / 4 of the original concentration, respectively, to obtain the repairing agent of Example 1-3.
Embodiment 4
[0040] Add 12g of diethylenetriamine penta(methylenephosphonic acid), 36g of succinic acid-modified chitosan of Preparation Example 1, 12g of sodium metaaluminate, and 32g of concentrated hydrochloric acid (37%) into 908g of deionized water , heated to 35° C. under stirring to dissolve completely, and after cooling, the repairing agent of Example 4 was obtained.
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