Cationic monomer with benzene ring, air-entraining type anti-mud agent for polycarboxylate superplasticizer using cationic monomer and preparation method of air-entraining type anti-mud agent
A technology of cationic monomer and anti-sludge agent, applied in the field of cationic monomer, can solve the problems of unstable performance, poor adaptability, increased dosage, etc., to solve the problem of large slump loss, improved state, and strong anti-sludge performance Effect
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[0045] A method for preparing an air-entraining anti-mud agent for a polycarboxylate water reducer, the specific preparation comprising:
[0046] (1) Preparation of cationic monomer with benzene ring: Mix 0.1mol p-phenol, 0.101mol dibromoethane, 0.01mol sodium hydroxide and 80mL ethanol in a reactor, reflux at 80°C for 10h, then add 0.101 mol N, N-dimethyl dodecylamine, continue the reflux reaction for 24h, recover the solvent after the reaction, and prepare the cationic monomer with benzene ring for use;
[0047] (2) Preparation of polyether chains with benzene rings: put 1 mol of phenoxyethanol and 0.05 mol of sodium methoxide in a reaction kettle, seal it, and exchange it with nitrogen gas for 2 to 3 times to remove the air in the kettle; heat up to 110°C, Under the condition that the reaction pressure is 0.5Mpa, slowly feed 50mol ethylene oxide into the reactor, mature for 3h, then cool down and degas the material to obtain the polyether chain with benzene ring;
[0048] ...
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