Biodegradable high-performance modified particle material and preparation method thereof

A technology of modified particles and biodegradation, applied in the field of biodegradable materials, can solve the problems of lack of hydrophobicity and antibacterial properties, inability to achieve natural degradation of waste, environmental pollution, etc., and achieve good biodegradability and use stability , good theory and practical significance, the effect of reducing costs

Pending Publication Date: 2021-12-14
广州绿徽新材料研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This material has the advantages of good durability and strong plasticity, but it has the disadvantages that it cannot realize t...

Method used

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  • Biodegradable high-performance modified particle material and preparation method thereof

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Effect test

Embodiment 1

[0118] A biodegradable high performance modified particulate material, prepared from the following raw materials by weight: 90 parts by oxide modified high amylose corn starch, 1-ethyl-3-methylimidazolium acetate 6.5 parts, poloxamines Farm 3.5 parts, corn distillers dried powder, 4 parts of concentrate, 4 parts of coconut husk powder, 3 parts of the modifier composition, PLA 20 parts of polylactic acid, poly (3-hydroxybutyrate -co-3- hydroxyhexanoate) PHBHHx7 parts, BASF ADR epoxy-functional chain extenders, 1 part of maleic anhydride, 0.7 parts of polyoxyethylene (the PEO) 0.7 parts, 4 parts of modified nano carbon fibers, nano calcium carbonate 10 parts; the preparation method comprising the steps of:

[0119] ① weighed according to the composition ratio by weight: high amylose corn starch, 90 parts of 1-ethyl-3-methylimidazolium acetate 6.5 parts, 3.5 parts poloxamer added together in a high speed mixer, sealed lid, stirring 5- after 12 minutes at room temperature, ultrasonic ...

Embodiment 2

[0127] A biodegradable high performance modified particulate material, parts by weight of the following raw materials: 90 parts of oxidatively modified high amylose wheat starch, 1-ethyl-3-methylimidazolium acetate 5 parts of an epoxy large 5 parts of soybean oil, 5 parts of betel nut shell powder, wheat powder, dried and concentrated vinasse 3 parts, 3 parts of the modifier composition, a polylactic acid PLA 20 parts of the epoxy-functional BASF ADR 0.9 parts of chain extender, 0.7 parts of maleic anhydride, polyoxyethylene (PEO) 0.8 parts, 7 parts of a modified carbon nanofiber, octadecyl quaternary ammonium modified nanoclays 15 parts; the preparation method comprising the steps of:

[0128] ① weighed according to the composition ratio by weight: high amylose wheat starch, 90 parts of 1-ethyl-3-methylimidazolium acetate 5 parts, 5 parts of epoxidized soybean oil added to the common high-speed mixer, sealed lid, stirring 5- after 12 minutes at room temperature, ultrasonic vibrat...

Embodiment 3

[0137] A modified particulate material of high performance biodegradable, made from the following raw materials by weight: 90 parts by oxidatively modified high amylose potato starch, 6 parts of lecithin, poloxamer, 4 parts of powder sugar cane vinasse concentrated to dryness 4 parts, 4 parts olive powder, 3 parts of the modifier composition, a polylactic acid PLA 20 parts by BASF ADR epoxy-functional chain extenders, 1 part of maleic anhydride, 0.6 parts of polyoxyethylene (PEO) 0.9 parts, change 8 parts of carbon nano fibers, nano-calcium carbonate 8 parts, 5 parts MWCNTs; preparation method comprising the steps of:

[0138] ① weighed according to the composition ratio by weight: high amylose potato starch 90 parts, 6 parts of lecithin, poloxamer added 4 parts of a common high-speed mixer, sealed lid, 5-12 minutes of stirring at room temperature, ultrasonic vibration 30min, ultrasonic power is 480W, and the resulting material placed in sealed 24h, standby;

[0139] ② weighed acc...

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Abstract

The invention relates to a biodegradable high-performance modified particle material and a preparation method thereof. The biodegradable high-performance modified particle material is prepared from polylactic acid PLA, a natural organic plant fiber material, oxidized modified high-amylose starch, a composite plasticizer, a combined modifier, a functional aid, a modifier, modified carbon nanofibers and an inorganic filler. By carrying out melting reaction extrusion at 55-185 DEG C through a double-stage serial screw granulating unit, and carrying out mixing, reaction, extrusion, cooling, cutting, drying, sterilization and packaging, the particle material is obtained. Various household and industrial products, toys, stationery and electronic product shells are produced by adopting universal equipment such as extrusion molding, plastic uptake or injection molding units. The adopted raw materials are rich in source, the raw material cost is low, the process is simple, the production cost is low, and the prepared particle material has high strength and good antibacterial performance, anti-aging performance and hydrophobic performance and can meet the requirements of various biodegradable hard material products.

Description

technical field [0001] The invention belongs to the technical field of preparing biodegradable materials, and in particular relates to a biodegradable high-performance modified material particle with ceramic texture and a preparation method thereof. Background technique [0002] According to UNEP's "Legal Restrictions on Single-Use Plastics and Microplastics: A Global Review of National Laws and Regulations", "Single-Use Plastics: A Roadmap for Sustainable Development" and announcements on the websites of relevant Chinese government departments, the European Union, and international agencies: Of the 192 countries in the world, as of July 2018, 127 countries (about 66%) have enacted some form of national laws and regulations restricting single-use plastics and plastic bags (65 countries have no restrictions on single-use plastics and microplastics ), which include bans, levies, and waste management measures to enhance disposal, encourage reuse and recycling, and promote alte...

Claims

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Application Information

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IPC IPC(8): C08L3/20
CPCC08L3/20C08L2201/06C08L2201/08C08L2205/16C08K2201/011C08K2003/2241C08K2003/265C08L2201/14C08K2003/0806C08L67/04C08L99/00C08L71/02C08L91/00C08K13/06C08K9/04C08K7/06C08K3/26C08K5/11C08K3/346C08K3/041C08K3/08
Inventor 谭卓华谭晓露黄炜岚
Owner 广州绿徽新材料研究院有限公司
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