Halogen-free low-smoke flame-retardant wire and cable and preparation method thereof

A wire and cable, low-smoke flame-retardant technology, applied in the field of halogen-free low-smoke flame-retardant wire and cable and its preparation, can solve the problems of decreasing oxygen index and reducing flame retardant performance, and achieves increasing heat capacity, improving flame retardant performance, and not easy ignition effect

Pending Publication Date: 2021-11-16
温州市电线二厂
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In view of the above-mentioned related technologies, in the current use of wires and cables, when the ambient temperature rises, the average activation energy of oxygen molecules increases, which is easy to enhance the efficiency of combining with the organic materials of wires and cables, and at the same time promotes more in the wires and cables. The cracking and gasification of organic materials in a unit time; therefore, some current wires and cables tend to have a significant drop in oxygen index and lower flame retardancy when the ambient temperature rises, so the inventor believes that there is still room for improvement

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045]This embodiment discloses a halogen-free low-smoke flame-retardant wire and cable and a preparation method thereof; a halogen-free low-smoke flame-retardant wire and cable includes a copper conductor and an insulating layer coated outside the copper conductor, and the insulating layer includes the following components: Parts: polytetrafluoroethylene, 2-(4-methoxyphenyl) malondialdehyde, silicone resin, aluminum hydroxide, ricinoleic acid, p-nitrobenzaldehyde and catalyst, wherein the catalyst is tellurium tetrachloride.

[0046] A preparation method of halogen-free low-smoke flame-retardant wire and cable, comprising the following steps:

[0047] S1. Preparation of wire and cable material for insulating layer; mix ricinoleic acid and catalyst, heat to 50°C, then add p-nitrobenzaldehyde while stirring, react for 20min; then add aluminum hydroxide, continue at a speed of 180r / min Stir for 30min, and naturally cool to room temperature to obtain modified aluminum hydroxide; ...

Embodiment 2

[0052] This embodiment discloses a halogen-free low-smoke flame-retardant wire and cable and a preparation method thereof; a halogen-free low-smoke flame-retardant wire and cable includes a copper conductor and an insulating layer coated outside the copper conductor, and the insulating layer includes the following components: Parts: polytetrafluoroethylene, 2-(4-methoxyphenyl) malondialdehyde, silicone resin, aluminum hydroxide, ricinoleic acid, p-nitrobenzaldehyde and catalyst, wherein the catalyst is tellurium tetrachloride.

[0053] A preparation method of halogen-free low-smoke flame-retardant wire and cable, comprising the following steps:

[0054] S1. Preparation of wire and cable material for insulating layer; mix ricinoleic acid and catalyst, heat to 60°C, then add p-nitrobenzaldehyde while stirring, react for 28min; then add aluminum hydroxide, continue at a speed of 200r / min Stir for 40min, and naturally cool to room temperature to obtain modified aluminum hydroxide;...

Embodiment 3

[0059] This embodiment discloses a halogen-free low-smoke flame-retardant wire and cable and a preparation method thereof; a halogen-free low-smoke flame-retardant wire and cable includes a copper conductor and an insulating layer coated outside the copper conductor, and the insulating layer includes the following components: Parts: polytetrafluoroethylene, 2-(4-methoxyphenyl) malondialdehyde, silicone resin, aluminum hydroxide, ricinoleic acid, p-nitrobenzaldehyde and catalyst, wherein the catalyst is tellurium tetrachloride.

[0060] A preparation method of halogen-free low-smoke flame-retardant wire and cable, comprising the following steps:

[0061] S1. Preparation of wire and cable material for insulating layer; mix ricinoleic acid and catalyst, heat to 55°C, then add p-nitrobenzaldehyde while stirring, react for 25min; then add aluminum hydroxide, continue at a speed of 190r / min Stir for 35min, and naturally cool to room temperature to obtain modified aluminum hydroxide;...

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Abstract

The invention relates to a halogen-free low-smoke flame-retardant electric wire and cable and a preparation method thereof, the halogen-free low-smoke flame-retardant electric wire and cable comprises a copper conductor and an insulating layer coating the copper conductor, and the insulating layer comprises the following components in parts by weight: 100-120 parts of polytetrafluoroethylene; 30 to 40 parts of 2-(4-methoxyphenyl) malonaldehyde; 5-6 parts of silicon resin; 12 to 15 parts of aluminum hydroxide; 8-10 parts of ricinoleic acid; 5 to 6 parts of p-nitrobenzaldehyde; and 1-2 parts of a catalyst. The preparation method of the halogen-free low-smoke flame-retardant electric wire and cable comprises preparation of an electric wire and cable material of an insulating layer and a cabling process. The halogen-free low-smoke flame-retardant electric wire and cable has the following advantages and effects: 2-(4-methoxyphenyl) malonaldehyde is easy to combine with polytetrafluoroethylene, and has a good flame retardant effect; the aluminum hydroxide reduces conduction heat resistance and is not easy to ignite; and in the presence of a catalyst, the aluminum hydroxide is modified by a product obtained by mixing the ricinoleic acid and the p-nitrobenzaldehyde, so that a good bonding interface is formed to form a continuous closed structure, and the flame retardant property is improved.

Description

technical field [0001] The present application relates to the technical field of wires and cables, in particular to a halogen-free, low-smoke, flame-retardant wire and cable and a preparation method thereof. Background technique [0002] Wire and cable refer to the wires that transmit electric energy. The existing electromagnetic wires are insulated wires that generate a magnetic field or induce current in a magnetic field after being energized. It is mainly used for motor and transformer windings and other related electromagnetic equipment. Its conductors are mainly copper. The wire should have a thin insulating layer and good electrical and mechanical properties, as well as heat resistance, moisture resistance, solvent resistance and other properties. [0003] The existing Chinese patent with publication number CN111145943A discloses a wire and cable for sensors, including a cable core and a cable outer layer. There are several cable cores in the cable outer layer, and eac...

Claims

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Application Information

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IPC IPC(8): C08L27/18C08L83/04C08L25/18C08K9/04C08K3/22C08K5/07C08K5/09C08K7/24C08K9/12C08K5/3412C08K5/315H01B3/44
CPCC08L27/18H01B3/445C08K2003/2227C08L2201/02C08L2203/202C08L83/04C08L25/18C08K9/04C08K3/22C08K5/07C08K5/09C08K7/24C08K9/12C08K5/3412C08K5/3155
Inventor 韩筱玉张希期
Owner 温州市电线二厂
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