Bactericidal composition containing isotianil and osthole
A technology of osthole and isotianil, which is applied in the direction of fungicides, biocides, biocides, etc., can solve the problems of general bactericidal effect, affecting rice yield, and rising rice planting costs
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Embodiment 1
[0030] A bactericidal composition containing Isotianil and osthole, comprising the following raw materials in weight percentage: 1% Isotianil, 0.1% osthole, 5% bactericidal auxiliary agent, phenylphenol polyoxyethyl ether phosphoric acid Add 10% ester, 1% ethanol, 1% polyethylene glycol, 0.9% silicone defoamer, and deionized water to 100%.
[0031] Described bactericidal auxiliary agent is made by following steps:
[0032] Step A1: Add methyl 1,2,4-triazole-3-carboxylate, potassium carbonate, and ethyl acetate into the reaction kettle, stir at a speed of 150r / min and add 1-chloro-3, 3,-Dimethyl-2-butanone was refluxed for 4 hours at a temperature of 60°C to obtain Intermediate 1, and Intermediate 1, aqueous sodium hydroxide solution, and methanol were added to the reaction kettle, and the Under the conditions of 200r / min and 35°C, the reaction was carried out for 1h, and the pH value of the reaction solution was adjusted to be neutral at room temperature to obtain intermediat...
Embodiment 2
[0037] A bactericidal composition containing Isotianil and osthole, comprising the following raw materials in weight percentage: 25% Isotianil, 8% osthole, 8% bactericidal auxiliary agent, phenylphenol polyoxyethyl ether phosphoric acid Add 10% ester, 1% ethanol, 1% polyethylene glycol, 0.9% silicone defoamer, and deionized water to 100%.
[0038] Described bactericidal auxiliary agent is made by following steps:
[0039] Step A1: Add methyl 1,2,4-triazole-3-carboxylate, potassium carbonate, and ethyl acetate into the reaction kettle, stir at a speed of 150r / min and add 1-chloro-3, 3,-Dimethyl-2-butanone was refluxed for 4 hours at a temperature of 65°C to obtain Intermediate 1, and Intermediate 1, aqueous sodium hydroxide solution, and methanol were added to the reaction kettle, and the Under the conditions of 300r / min and 35°C, the reaction was carried out for 2 hours, and the pH value of the reaction solution was adjusted to be neutral at room temperature to obtain interme...
Embodiment 3
[0044] A bactericidal composition containing Isotianil and osthole, comprising the following raw materials in weight percentage: 50% Isotianil, 10% osthole, 10% bactericidal auxiliary agent, 3% pull-off powder BX, 5% propylene glycol %, deionized water added to 100%.
[0045] Described bactericidal auxiliary agent is made by following steps:
[0046] Step A1: Add methyl 1,2,4-triazole-3-carboxylate, potassium carbonate, and ethyl acetate into the reactor, stir at a speed of 200r / min and add 1-chloro-3, 3,-Dimethyl-2-butanone was refluxed for 6 hours at a temperature of 65°C to obtain Intermediate 1, and Intermediate 1, aqueous sodium hydroxide solution, and methanol were added to the reaction kettle, and the 300r / min, under the condition of 40°C, react for 2h, lower to room temperature and adjust the pH value of the reaction solution to be neutral to obtain intermediate 2, intermediate 2, ethylenediamine, dimethyl sulfoxide, 1-Hydroxybenzotriazole was added into the reaction...
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