System and method for manufacturing heat shrinkable film
A manufacturing system and technology of heat shrinkable film, applied in the direction of flat products, household appliances, other household appliances, etc., can solve the problems of unavoidable agglomeration, unstable performance of film-forming products, large specific surface area, etc. Excellent transparency, light transmittance and high effect of unidirectional thermal shrinkage
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Embodiment 1
[0045] Add 5.0kg of terephthalic acid, 2.2kg of ethylene glycol, and 1.10g of germanium dioxide into a 20L general-purpose polymerization reactor, and carry out esterification reaction at 230-265°C and 0.2-0.3Mpa (gauge pressure). After reaching the theoretical value, the system pressure was released to normal pressure. To react under these conditions, add 1.025g of triethyl phosphate, stir at normal pressure for 10 minutes, raise the temperature and lower the pressure to 280°C and below 100Pa, carry out the reaction for 3 hours under these conditions, and finally extrude through polymerized melt, pelletize, After drying, PET polyester chips for films with an intrinsic viscosity of 0.75 dl / g were obtained.
[0046] Dry 60 parts by weight of airgel particles with a particle size of 0.5 μm at 120 ° C for 4 hours; dry 10 parts by weight of polylactic acid particles with a particle size of 0.5 mm or less at 110 ° C for 4 hours; Polystyrene particles below mm and 5 parts by weight...
Embodiment 2
[0050] Add 5.0kg of terephthalic acid, 2.2kg of ethylene glycol, and 1.10g of germanium dioxide into a 20L general-purpose polymerization reactor, and carry out esterification reaction at 230-265°C and 0.2-0.3Mpa (gauge pressure). After reaching the theoretical value, the system pressure was released to normal pressure. To react under these conditions, add 1.025g of triethyl phosphate, stir at normal pressure for 10 minutes, raise the temperature and lower the pressure to 280°C and below 100Pa, carry out the reaction for 3 hours under these conditions, and finally extrude through polymerized melt, pelletize, After drying, PET polyester chips for films with an intrinsic viscosity of 0.75 dl / g were obtained.
[0051] Dry 70 parts by weight of airgel particles with a particle diameter of 10 μm at 120 ° C for 4 hours; dry 15 parts by weight of polylactic acid particles with a particle size of 0.5 mm or less at 110 ° C for 4 hours; The following polystyrene pellets were dried at 1...
Embodiment 3
[0055] Add 5.0kg of purified terephthalic acid, 2.4kg of ethylene glycol, 1.6kg of 1,4-cyclohexanedimethanol (CHDM), 0.1g of tetrabutyl titanate catalyst, and 120g of calcium acetate anti-sticking agent into a 20L general-purpose reactor Binder, 20g nano-scale calcium acetate additive, carry out esterification reaction under the conditions of 230-250°C and 0.2-0.3Mpa, and release the system pressure to normal pressure after the water output reaches the theoretical value. React under these conditions, add 0.03g triethyl phosphate stabilizer, stir at normal pressure for 6min, after vacuuming, raise the temperature inside the reactor to 285°C, and drop the pressure below 100Pa, react under these conditions for 3h, and finally PETG polyester chips for films with an intrinsic viscosity of 0.80 dl / g were obtained through polymerization melt extrusion, pelletizing and drying.
[0056] Dry 65 parts by weight of airgel particles with a particle size of 5 μm at 120 ° C for 4 hours; dry ...
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