Plastic laminate, preparation method thereof and plastic molded product
A manufacturing method and technology of plastic layers, applied in chemical instruments and methods, coatings, layered products, etc., can solve problems such as crimp dimensional stability, thermal shrinkage difference between layers, etc.
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experiment example 1
[0126] 1A. Preparation of membrane
[0127] PET films or PC films (samples 1-1 to 1-7) were prepared in single layers of various thicknesses. In addition, films (samples 1-9 and 1-11) in which two of the above-mentioned PET film or PC film were laminated were prepared.
[0128] In addition, a hard coat film (samples 1-8) was prepared by coating a hard coat (HC) resin composition having a thickness of about 15 μm on the above-mentioned PET film. At this time, by mixing 47.6 parts by weight of urethane acrylate oligomer resin (MIRAMERPU620NT, Miwon), 1.7 parts by weight of curing agent (Irgacure 184, Ciba) and 50.7 parts by weight Parts by weight of the solvent (toluene) to prepare the hard coat resin composition. The above-mentioned hard coat resin composition is coated on the surface of the substrate layer using a Meyer bar coater, etc., and dried at 80°C for 1 minute, and then heated at 400 mJ / cm 2 The conditions for UV curing.
[0129] In addition, two hard coat films prepared a...
experiment example 2
[0137] 2A. Preparation of membrane
[0138] Prepare PET film or PC film in various thicknesses. A film (samples 2-2, 2-4, 2-6 to 2-10) laminated with the above-mentioned PET film and / or PC film was prepared.
[0139] In addition, a hard coat film was prepared by coating a hard coat (HC) resin composition with a thickness of about 15 μm on the above-mentioned PET film, and the hard coat film was laminated with the PET film and / or PC film (Sample 2 -1, 2-3, 2-5). At this time, the preparation, coating, and curing conditions of the hard coat resin composition are the same as those in Experimental Example 1.
[0140] When the film is laminated, an adhesive with a thickness of about 5 μm is applied on the contact surface for bonding, and the type of adhesive, application and curing conditions are the same as in Experimental Example 1 above.
[0141] 2B. Test
[0142] For each film sample prepared, the curl change was tested in the same manner as in Experimental Example 1 above except that...
experiment example 3
[0148] 3A. Preparation of membrane
[0149] A hard coat film was prepared by coating a hard coat (HC) resin composition having a thickness of about 15 μm on the above PET film, and the hard coat film was laminated with a PC film and a PET film (Sample 3-1). At this time, the preparation, coating, and curing conditions of the hard coat resin composition are the same as those in Experimental Example 1.
[0150] In addition, hard coat films (Sample 3-2 to Sample 3-5) were laminated on both surfaces of the PC film as the center. At this time, the thickness of the hard coat layer is controlled in the range of 9 μm to 15 μm by diluting the hard coat resin composition.
[0151] When the film is laminated, an adhesive with a thickness of about 5 μm is applied on the contact surface for bonding, and the type of adhesive, application and curing conditions are the same as in Experimental Example 1 above.
[0152] 3B. Test
[0153] For each film sample prepared, the curl change was tested in the ...
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