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Compound containing polyheterocycles and application

A compound and heterocyclic technology, applied in the field of organic electroluminescence materials, can solve the problems of reduced lifespan, low electron mobility, and high device operating voltage

Active Publication Date: 2020-10-09
北京燕化集联光电技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since the development of organic charge transport materials, there are many kinds of hole transport materials and good performance, while there are few varieties of electron transport materials and poor performance.
For example, the currently commonly used electron transport material Alq3 has a low electron mobility, which leads to a high operating voltage of the device and serious power consumption; some electron transport materials such as LG201 have a low triplet energy level. When using phosphorescent materials as the light-emitting layer, It is necessary to increase the exciton blocking layer, otherwise the efficiency will decrease; there are also some materials such as Bphen, which are easy to crystallize, resulting in a decrease in lifetime
These problems in electron transport materials are the bottlenecks affecting the development of organic electroluminescent display devices

Method used

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  • Compound containing polyheterocycles and application
  • Compound containing polyheterocycles and application
  • Compound containing polyheterocycles and application

Examples

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preparation example Construction

[0056] According to the preparation method provided by the present invention, those skilled in the art can use known common means to realize, such as further selecting suitable catalysts, solvents, determining suitable reaction temperature, time, material ratio, etc., the present invention is not particularly limited to this . Unless otherwise specified, the solvents, catalysts, bases and other raw materials used in the preparation process can be synthesized through open commercial channels or methods known in the art.

[0057] Synthetic intermediates M1~M10

[0058] Synthesis of Intermediate M1

[0059]

[0060] The synthetic route is as follows:

[0061]

[0062] The specific operation steps are:

[0063](1) In a 2L three-necked flask equipped with mechanical stirring, add 4-chloro-1-fluoro-2-nitrobenzene (17.5g, 0.1mol), 2-bromo-4-chloroaniline (30.8g, 0.15mol ), stirred, protected by argon, heated up to 180°C, and kept warm for more than 30 hours. During the reac...

Embodiment 1

[0111]

[0112] The synthetic route is as follows:

[0113]

[0114] The synthesis of compound 1-6 comprises the following specific steps:

[0115] Take a 2L three-neck flask, equip it with magnetic stirring, add M1 (41.2g, 0.1mol), (4-phenylquinazolin-2-yl) boric acid (75.0g, 0.3mol), cesium carbonate (117g, 0.36mol) and 800ml of dioxane, start stirring. After nitrogen replacement again, (2.2 g, 11 mmol) tri-tert-butylphosphine and (4.1 g, 4.5 mmol) tris(dibenzylideneacetone) dipalladium were added. After the addition, heat up to raise the temperature, control the temperature at 80-90°C for 4 hours, and cool down after the reaction. Adjust to neutrality, separate the organic phase, extract, dry, perform column chromatography, and spin dry the solvent to obtain 70.1 g of a light yellow solid with a yield of about 76%.

[0116] Product MS (m / e): 922.35; Elemental analysis (C 64 h 42 N 8 ): theoretical value C: 83.27%, H: 4.59%, N: 12.14%; measured value C: 83.03%, H...

Embodiment 2

[0118]

[0119] The synthetic route is as follows:

[0120]

[0121] The synthesis of compound I-16: replace M1 with M2, benzo [d] thiazol-2-yl boronic acid replaces (4-phenylquinazolin-2-yl) boronic acid, select the appropriate material ratio, other raw materials and steps are all Same as Example 1, 49.5 g light yellow solid was obtained, the yield was about 86%.

[0122] Product MS (m / e): 576.14; Elemental analysis (C 36 h 24 N 4 S 2 ): theoretical value C: 74.97%, H: 4.19%, N: 9.71%; measured value C: 74.71%, H: 3.96%, N: 9.48%.

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Abstract

The invention relates to the technical field of organic electroluminescent display, particularly discloses an organic material containing a polyheterocyclic compound, and also discloses an applicationof the organic material in an organic electroluminescent device. The polyheterocycle-containing compound provided by the invention is shown as a general formula (I), can be applied to the field of organic electroluminescence, and can be used as an electron transport material. The compound with the structure provided by the invention is applied to an OLED device, the driving voltage of the devicecan be reduced, and the light emitting efficiency of the device is improved.

Description

technical field [0001] The invention relates to the technical field of organic electroluminescent materials, specifically discloses a novel polyheterocyclic compound and its application in organic electroluminescent devices. Background technique [0002] The application of organic electroluminescent (OLED) materials in information display materials, organic optoelectronic materials and other fields has great research value and bright application prospects. With the development of multimedia information technology, the performance requirements of flat panel display devices are getting higher and higher. At present, the main display technologies include plasma display devices, field emission display devices and organic electroluminescence display devices (OLEDs). Among them, OLEDs have a series of advantages such as self-luminescence, low-voltage DC drive, light and thin power saving, full curing, wide viewing angle, and rich colors. Compared with liquid crystal display devic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07D487/04C07D519/00C09K11/06H01L51/50H01L51/54
CPCC07D487/04C07D519/00C09K11/06C09K2211/1011C09K2211/1029C09K2211/1033C09K2211/1037C09K2211/1044C09K2211/1059C09K2211/1088H10K85/626H10K85/615H10K85/654H10K85/6574H10K85/657H10K85/6572H10K50/16
Inventor 梁现丽程丹丹范洪涛段陆萌杭德余曹占广班全志陈婷
Owner 北京燕化集联光电技术有限公司
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