Two-component latent metal carbene catalytic system, dicyclopentadiene polymerization double-material system and polydicyclopentadiene composite material
A technology of dicyclopentadiene and metal carbene, which is applied in the field of polydicyclopentadiene composite materials and dicyclopentadiene polymerization dual-material systems, can solve the problems of short storage time and unfavorable large-scale production, and achieve cost reduction and easy Promoted app performance
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Embodiment 1
[0044] The two-component latent metal carbene catalytic system of this embodiment is a latent ruthenium carbene catalytic system, which consists of a mixture of ruthenium carbene and tributylphosphine, 3-bromo-1-propene (CH 2 =CHCH 2 Br) composition, the molar ratio of ruthenium carbene to tributylphosphine is 1:1, and the molar ratio of tributylphosphine to 3-bromo-1-propene is 1:20.
Embodiment 2
[0046] The two-component latent metal carbene catalytic system of this embodiment is a latent ruthenium carbene catalytic system, which is composed of a mixture of ruthenium carbene and triphenylphosphine and benzyl bromide, and the molar ratio of ruthenium carbene to triphenylphosphine is 1: 50. The molar ratio of triphenylphosphine to benzyl bromide is 1:100.
Embodiment 3
[0048] The two-component latent metal carbene catalytic system of this embodiment is a latent ruthenium carbene catalytic system, which consists of a mixture of ruthenium carbene and tributylphosphine, 3-bromo-1-propene (CH 2 =CHCH 2 Br) composition, the molar ratio of ruthenium carbene to tributylphosphine is 1:10, and the molar ratio of tributylphosphine to 3-bromo-1-propene is 1:50.
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