Synthetic leather of organosilicon composite polyurethane and preparation method thereof
A composite polyurethane and silicone technology, which is applied in the field of synthetic leather manufacturing, can solve problems such as large pinholes, hydrolysis resistance, salt spray resistance, and affect appearance, and achieve low VOCs emissions, soft and plump feel, and outstanding hydrolysis resistance. Effect
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Embodiment 1
[0033] The synthetic leather of organic silicon compound polyurethane of this embodiment, it is made up of two layers of materials from top to bottom, is respectively organic silicon surface layer, polyurethane bass;
[0034] The silicone surface layer is composed of the following raw materials in parts by weight: 100 parts of vinyl-terminated polydimethylsiloxane (viscosity: 5000mpa.s, vinyl content: 0.16%), methylphenyl silicon 15 parts of resin (molecular weight: 4000), 3 parts of trimethyl-terminated hydrogen-containing polysiloxane (hydrogen content: 0.5%, viscosity: 500mpa.s), fumed silica (specific table: 200m 2 / g) 20 parts, tetramethylcyclotetrasiloxane and allyl glycidyl ether addition compound (hydrogen content: 0.32%) 2 parts, color paste 3 parts, platinum catalyst (isopropanol ethanol solution, 5000ppm) 1 part, 1-ethynyl-1-cyclohexanol 0.3 part, the molar ratio of active hydrogen and vinyl in the formula is: 3.6.
[0035] The production method of the synthetic le...
Embodiment 2
[0037] In this embodiment, the synthetic leather of organosilicon composite polyurethane is composed of two layers of materials from top to bottom, which are respectively organosilicon surface layer and polyurethane bass.
[0038] The silicone surface layer is composed of the following raw materials in parts by weight: 100 parts of vinyl-terminated polydimethylsiloxane (viscosity: 10000mpa.s, vinyl content: 0.13%), vinylphenyl silicon 30 parts of resin (molecular weight: 4000, vinyl content: 2.5%), 5 parts of trimethyl-terminated hydrogen-containing polysiloxane (hydrogen content: 1.0%, viscosity: 30mpa.s), fumed silica (ratio Table: 200m 2 / g) 20 parts, addition compound of tetramethylcyclotetrasiloxane and allyl glycidyl ether (hydrogen content: 0.32%) 1.5 parts, color paste 3 parts, platinum catalyst (isopropanol ethanol solution, 5000ppm) 1 part, 1-ethynyl-1-cyclohexanol 0.3 part, the molar ratio of active hydrogen and vinyl in the formula is: 1.68.
[0039] The producti...
Embodiment 3
[0041] The synthetic leather of organic silicon compound polyurethane of this embodiment, it is made up of two layers of materials from top to bottom, is respectively organic silicon surface layer, polyurethane bass;
[0042] The silicone surface layer is composed of the following raw materials in parts by weight: 100 parts of vinyl-terminated polydimethylsiloxane (viscosity: 5000mpa.s, vinyl content: 0.16%), methylphenyl silicon 26 parts of resin (molecular weight: 4000), 4 parts of trimethyl-terminated hydrogen-containing polysiloxane (hydrogen content: 0.5%, viscosity: 500mpa.s), fumed silica (specific table: 200m 2 / g) 20 parts, tetramethylcyclotetrasiloxane and allyl glycidyl ether addition compound (hydrogen content: 0.32%) 2 parts, color paste 3 parts, platinum catalyst (isopropanol ethanol solution, 5000ppm) 1 part, 1-ethynyl-1-cyclohexanol 0.3 part, the molar ratio of active hydrogen and vinyl in the formula is: 4.45.
[0043] The preparation method of this embodimen...
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