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White fluorescent carbon dot and preparation method thereof

A fluorescent carbon dot, white technology, applied in the field of white fluorescent carbon dots and its preparation, can solve the problems of difficult doping of quantum dots and difficult preparation of white fluorescence, and achieve high fluorescence quantum yield, low toxicity and good biocompatibility , the effect of a wide range of application prospects

Inactive Publication Date: 2020-03-17
JIANGSU ANNATAI ENVIRONMENTAL PROTECTION TECH CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to provide a kind of white fluorescent carbon dot and preparation method thereof in order to overcome the deficiencies in the prior art, the method is simple and easy, the preparation efficiency and finished product pass rate are high, economic value, social value, ecological value and popularization and application High value; the prepared white fluorescent carbon dots have low toxicity and good biocompatibility, high fluorescence intensity, stable storage and high fluorescence quantum yield, which effectively solves the difficulty of quantum dot doping in the existing technology, and the white Technical Problems of Difficult Preparation of Fluorescence

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  • White fluorescent carbon dot and preparation method thereof
  • White fluorescent carbon dot and preparation method thereof

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preparation example Construction

[0027] The present invention relates to a kind of preparation method of white fluorescent carbon dot, is characterized in that, comprises the following steps:

[0028] Step S1, preparation of precursor I: dissolving citric acid in an anhydrous alcohol solvent and stirring evenly to obtain precursor I;

[0029] Step S2, preparation of precursor II: dissolving o-phenylenediamine in absolute ethanol, and stirring evenly to obtain precursor II;

[0030] Step S3, preparation of precursor III: dissolving hydrogen peroxide solution in absolute ethanol, and stirring evenly to obtain precursor III;

[0031] Step S4, preparation of carbon dots: After mixing the precursor I made by step S1, the precursor II made by step S2 and the precursor III made by step S3 according to the volume ratio of 1:1:1 , to obtain the mixed material, and then transfer the mixed material to the liner of the PTFE hydrothermal reaction kettle for ultrasonic treatment for 25-35min, then transfer to the hydrothe...

Embodiment 1

[0041] Embodiment 1 provides a kind of preparation method of white fluorescent carbon dot, comprises the steps:

[0042] Step S1: Dissolving 18 mg of citric acid in 15 mL of absolute ethanol to obtain precursor I;

[0043] Step S2: dissolving 108 mg of o-phenylenediamine in 15 mL of absolute ethanol to obtain precursor II;

[0044] Step S3: Dissolving 3ml of 30% hydrogen peroxide in 15mL of absolute ethanol to obtain precursor III;

[0045] Step S4: Mix the precursors III, II and precursor 1 at a volume ratio of 1:1:1, transfer to a 50mL polytetrafluorothermal reaction liner for ultrasonic treatment for 30min, then transfer to a hydrothermal oven, and heat to 180 The carbon dots obtained by hydrothermal reaction at ℃ for 12 hours and cooled to room temperature with the furnace;

[0046]Step S5: Dilute the carbon dots 4 times with absolute ethanol, and irradiate with a 365nm ultraviolet lamp to obtain cool white fluorescence.

[0047] Such as figure 1 To prepare the UV-Visa...

Embodiment 2

[0049] Embodiment 2 provides a kind of preparation method of white fluorescent carbon dot, comprises the steps:

[0050] Step S1: Dissolving 18 mg of citric acid in 15 mL of absolute ethanol to obtain precursor I;

[0051] Step S2: dissolving 108 mg of o-phenylenediamine in 15 mL of absolute ethanol to obtain precursor II;

[0052] Step S3: Dissolving 1ml of 30% hydrogen peroxide in 15mL of absolute ethanol to obtain precursor III;

[0053] Step S4: Mix precursors III, II and precursor 1 at a volume ratio of 1:1:1, transfer to a 50mL PTFE hydrothermal reaction liner for ultrasonic treatment for 30min, then transfer to a hydrothermal oven, heat to 180 The carbon dots obtained by hydrothermal reaction at ℃ for 12 hours and cooled to room temperature with the furnace;

[0054] Step S5: Dilute the carbon dots 3 times with absolute ethanol, and irradiate with a 365nm ultraviolet lamp to obtain cool white fluorescence. The particle size of the prepared carbon dots is 5-20nm. The...

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Abstract

The invention relates to a preparation method of a white fluorescent carbon dot. The preparation method comprises the following steps: S1, preparing a precursor I; S2, preparing a precursor II; S3, preparing a precursor III; S4, preparing a carbon dot; and S5, preparing the white fluorescent carbon dot. The invention also discloses the white fluorescent carbon dot prepared by the preparation method of the white fluorescent carbon dot. The preparation method of the white fluorescent carbon dots is simple and feasible, has a high preparation efficiency and a high finished product qualified rate,and has high economic values, high social values, high ecological values and high promotion and application values; and the prepared white fluorescent carbon dot has the advantages of low toxicity, good biocompatibility, high fluorescence intensity, high storage stability and high fluorescence quantum yield, and effectively solves the technical problems that quantum dots are difficult to dope andwhite fluorescent carbon dot is difficult to prepare in the prior art.

Description

technical field [0001] The invention relates to the technical field of new materials, in particular to a white fluorescent carbon dot and a preparation method thereof. Background technique [0002] In recent years, quantum dots, as the latest carbon material, have attracted the favor of nanomaterial researchers because of their excellent optical properties and low biological toxicity. Quantum dots exhibit excellent properties such as hydrophilicity, low cytotoxicity, chemical and photostability, etc., making them widely concerned and applied in the fields of chemistry, biomedicine, sensing and optoelectronics. [0003] The preparation of quantum dots is an important topic in the field of carbon materials research. At present, there are two main categories: bottom-up methods and bottom-up methods. In addition, the doping of heterocyclic elements can change the energy band structure and surface functional group structure of quantum dots to a large extent, which in turn leads...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K11/65C01B32/15B82Y20/00B82Y40/00
CPCB82Y20/00B82Y40/00C01B32/15C09K11/65
Inventor 谢晓峰
Owner JIANGSU ANNATAI ENVIRONMENTAL PROTECTION TECH CO LTD
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