White fluorescent carbon dot and preparation method thereof
A fluorescent carbon dot, white technology, applied in the field of white fluorescent carbon dots and its preparation, can solve the problems of difficult doping of quantum dots and difficult preparation of white fluorescence, and achieve high fluorescence quantum yield, low toxicity and good biocompatibility , the effect of a wide range of application prospects
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[0027] The present invention relates to a kind of preparation method of white fluorescent carbon dot, is characterized in that, comprises the following steps:
[0028] Step S1, preparation of precursor I: dissolving citric acid in an anhydrous alcohol solvent and stirring evenly to obtain precursor I;
[0029] Step S2, preparation of precursor II: dissolving o-phenylenediamine in absolute ethanol, and stirring evenly to obtain precursor II;
[0030] Step S3, preparation of precursor III: dissolving hydrogen peroxide solution in absolute ethanol, and stirring evenly to obtain precursor III;
[0031] Step S4, preparation of carbon dots: After mixing the precursor I made by step S1, the precursor II made by step S2 and the precursor III made by step S3 according to the volume ratio of 1:1:1 , to obtain the mixed material, and then transfer the mixed material to the liner of the PTFE hydrothermal reaction kettle for ultrasonic treatment for 25-35min, then transfer to the hydrothe...
Embodiment 1
[0041] Embodiment 1 provides a kind of preparation method of white fluorescent carbon dot, comprises the steps:
[0042] Step S1: Dissolving 18 mg of citric acid in 15 mL of absolute ethanol to obtain precursor I;
[0043] Step S2: dissolving 108 mg of o-phenylenediamine in 15 mL of absolute ethanol to obtain precursor II;
[0044] Step S3: Dissolving 3ml of 30% hydrogen peroxide in 15mL of absolute ethanol to obtain precursor III;
[0045] Step S4: Mix the precursors III, II and precursor 1 at a volume ratio of 1:1:1, transfer to a 50mL polytetrafluorothermal reaction liner for ultrasonic treatment for 30min, then transfer to a hydrothermal oven, and heat to 180 The carbon dots obtained by hydrothermal reaction at ℃ for 12 hours and cooled to room temperature with the furnace;
[0046]Step S5: Dilute the carbon dots 4 times with absolute ethanol, and irradiate with a 365nm ultraviolet lamp to obtain cool white fluorescence.
[0047] Such as figure 1 To prepare the UV-Visa...
Embodiment 2
[0049] Embodiment 2 provides a kind of preparation method of white fluorescent carbon dot, comprises the steps:
[0050] Step S1: Dissolving 18 mg of citric acid in 15 mL of absolute ethanol to obtain precursor I;
[0051] Step S2: dissolving 108 mg of o-phenylenediamine in 15 mL of absolute ethanol to obtain precursor II;
[0052] Step S3: Dissolving 1ml of 30% hydrogen peroxide in 15mL of absolute ethanol to obtain precursor III;
[0053] Step S4: Mix precursors III, II and precursor 1 at a volume ratio of 1:1:1, transfer to a 50mL PTFE hydrothermal reaction liner for ultrasonic treatment for 30min, then transfer to a hydrothermal oven, heat to 180 The carbon dots obtained by hydrothermal reaction at ℃ for 12 hours and cooled to room temperature with the furnace;
[0054] Step S5: Dilute the carbon dots 3 times with absolute ethanol, and irradiate with a 365nm ultraviolet lamp to obtain cool white fluorescence. The particle size of the prepared carbon dots is 5-20nm. The...
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