A kind of organic compound, composition comprising it, organic electronic device and application
A technology of organic mixtures and organic materials, applied in electroluminescent devices, in the field of organic mixtures, it can solve problems such as interface erosion and interface miscibility, and achieve low cost, good solubility and film-forming properties, and excellent resistance to The effect of solvent properties
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[0174] compound synthesis
[0175]
[0176] The above-mentioned materials M1 to M5 are currently commercially available products, wherein M1 (CAS: 124-09-4) has a purity of 99.5% and a boiling point of 204° C., and M2 (CAS: 1072-21-5) has a purity of 99% and a boiling point of 190° C. M3 (CAS: 106-51-4) purity 99% boiling point 293°C, M4 (CAS: 9003-39-8), M5 (CAS: 556-18-3) purity 99.0% boiling point 138°C.
[0177] 1. Synthesis of polymers
[0178] Synthesis of Polymer P1
[0179]
[0180] In a 25mL two-necked round bottom flask, add 0.586g (1.0mmol) monomer a, 0.431g (1.0mmol) monomer b, 20mg Pd (PPh 3 ) 4 , 10 mL of degassed toluene and 2 mL of a 20% mass fraction of tetraethylammonium hydroxide aqueous solution, stir evenly, pass N 2 15 minutes. react in N 2 The reaction was carried out at 110°C for 24 hours, 0.2 mL of bromobenzene was added for 2 hours, and 0.2 g of phenylboronic acid was added for 2 hours. After the reaction was cooled to room temperature, t...
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