All-vanadium redox flow battery energy storage system equivalent method based on electric-thermal coupling

An all-vanadium flow battery and energy storage system technology, which is applied in the field of battery modeling in power systems, and can solve problems such as affecting the safe and efficient operation of batteries, failing to consider errors, and failing to consider the impact of temperature on flow batteries.

Active Publication Date: 2019-09-24
WUHAN UNIV OF TECH +1
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Problems solved by technology

Improper temperature control will lead to precipitation of reactants and even blockage of flow channels, which will affect the safe and efficient operation of the battery
However, the existing electrical equivalent models do not consider the influence of temperature on the external characteristics of flow batteries
In the current research, the patent "An Equivalent Simulation Method for All Vanadium Redox Flow Battery Energy Storage System" (Patent No.: 201410089721.4) proposed a second-order dynamic equivalent model; ") compared and analyzed the basic principles and respective characteristics of different equivalent circuit models, and proposed a commonly used equivalent model; The vanadium redox flow battery energy storage system modeling research is carried out. In this paper, it is assumed that the temperature remains constant during the reaction process, and the error caused by the large difference between the set temperature and the actual operating temperature is not considered.

Method used

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  • All-vanadium redox flow battery energy storage system equivalent method based on electric-thermal coupling
  • All-vanadium redox flow battery energy storage system equivalent method based on electric-thermal coupling
  • All-vanadium redox flow battery energy storage system equivalent method based on electric-thermal coupling

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Embodiment Construction

[0064] The present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments.

[0065] The present invention proposes an equivalent method for an all-vanadium redox flow battery energy storage system based on electrothermal coupling, including establishing a mathematical model of an all-vanadium redox flow battery, performing parameter identification on the mathematical model of an all-vanadium redox flow battery, and using a genetic algorithm to The instantaneous energy efficiency of the vanadium redox flow battery is optimized in real time to obtain the highest instantaneous energy efficiency when operating under different SOCs, as well as the flow rate, temperature and current value corresponding to the efficiency.

[0066] In the specific example, a 5kW / 3.3kWh all-vanadium redox flow battery is used as an example to describe, and the parameters of the all-vanadium redox flow battery are shown in Table 1.

[0...

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Abstract

The invention discloses an all-vanadium redox flow battery energy storage system equivalence method based on electric-thermal coupling. The method comprises: 1, performing modeling on electrical characteristics of a VRB according to a second-order resistance-capacitance network; 2, performing parameter identification by using a particle swarm algorithm; 3, analyzing the heat production condition of each module in the operation of the battery; 4, analyzing the heat transfer process of the VRB system; 5, based on an electric-thermal ratio fitting principle, a heat transfer path being equivalent; and 6, combining all the states obtained in the step 2 and the step 5 to obtain a complete state space equation of the VRB energy storage system electric heating coupling model. According to the method, the electrical characteristics and the heat generation characteristics of the VRB energy storage system during operation and the coupling relation between the electrical characteristics and the heat generation characteristics are comprehensively considered, the charge state, the terminal voltage and the temperature states of all parts of the battery can be accurately predicted, and safe and stable operation of the VRB is effectively guaranteed.

Description

technical field [0001] The invention relates to the technical field of electric power system battery modeling, specifically refers to an equivalent method for an all-vanadium redox flow battery energy storage system based on electrothermal coupling, and proposes an electrical equivalent model suitable for power grid energy storage system simulation. Background technique [0002] With the aggravation of environmental pollution and energy crisis, it is particularly important to use renewable energy such as solar energy, wind energy, and water energy to generate electricity. However, the inherent randomness and intermittent characteristics of renewable energy seriously hinder the safe and economical operation of the grid system. The dispatchability of the energy storage system can effectively improve the problems caused by the instability of new energy power generation. All-vanadium redox flow batteries have become one of the preferred technologies for large-scale energy stora...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G06F17/50
CPCG06F30/20
Inventor 熊斌宇杨叶森刘正奇李旸唐金锐苏义鑫谢长君陈继忠
Owner WUHAN UNIV OF TECH
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