Light-shielding sliding film, light-shielding sliding member, and resin composition for light-shielding sliding film
A technology of light-shielding and binder resins, which is applied in the field of light-shielding sliding parts, resin compositions for light-shielding sliding films, and light-shielding sliding films. It can solve the problems of easy falling off of particles, increase design freedom, and improve dispersion excellent properties, film strength and abrasion resistance
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[0072] Hereinafter, although an Example and a comparative example are given and this invention is demonstrated in detail, this invention is not limited to these Examples at all. The present invention can adopt various conditions within the scope not departing from the gist of the present invention and achieving the object of the present invention. In addition, below, unless there is a description in particular, "part" means a "mass part".
[0073] [Preparation of resin composition (coating liquid)]
preparation example 1
[0075] The resin composition (solid content concentration: 29.8 mass %) of the compounding composition shown below was prepared.
[0076] ・73.6 parts by mass of urethane-based binder resin (NCO / OH ratio: 1.23)
[0077] Acrylic polyol component
[0078] (ACRYDIC A804: manufactured by DIC Corporation, OH value: 40, solid content: 50% by mass)
[0079] Polyisocyanate Curing Agent Components
[0080] (TAKENATE D110N: manufactured by Mitsui Chemicals, NCO value: 11.5, solid content: 75% by mass)
[0081] 13.2 parts by mass of carbon black
[0082] (VULCAN XC-72R: manufactured by Cabot Corporation, average primary particle size: 30nm, aggregate particle size: 0.4μm)
[0083] 13.2 parts by mass of granular wax
[0084] (Ceridust 3620: manufactured by Clariant Chemicals, average particle diameter D 50 : 7.5~9.5μm)
[0085] ·Leveling agent 0.2 parts by mass
[0086] (Silicone-based additive M-ADDITIVE: manufactured by Tosoh Dow Corning Corporation)
[0087] · Diluting solvent ...
preparation example 2
[0090] The resin composition (solid content concentration: 29.8 mass %) of the compounding composition shown below was prepared.
[0091] · Urethane-based binder resin (NCO / OH ratio: 1.30) 73.6 parts by mass
[0092] Acrylic polyol component
[0093] (ACRYDIC A804: manufactured by DIC Corporation, OH value: 40, solid content: 50% by mass)
[0094] Polyisocyanate Curing Agent Components
[0095] (TAKENATE D110N: manufactured by Mitsui Chemicals, NCO value: 11.5, solid content: 75% by mass)
[0096] 13.2 parts by mass of carbon black
[0097] (VULCAN XC-72R: manufactured by Cabot Corporation, average primary particle size: 30nm, aggregate particle size: 0.4μm)
[0098] 13.2 parts by mass of granular wax
[0099] (Ceridust 3620: manufactured by Clariant Chemicals, average particle diameter D 50 : 7.5~9.5μm)
[0100] ·Leveling agent 0.2 parts by mass
[0101] (Silicone-based additive M-ADDITIVE: manufactured by Tosoh Dow Corning Corporation)
[0102] · Diluting solvent
...
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